Solvent Extraction of Palladium from Chloride Media by TBP

被引:0
|
作者
Sadeghi, N. [1 ,2 ]
Alamdari, E. K. [1 ,3 ]
Sadeghi, N. [1 ,2 ]
Alamdari, E. K. [1 ,3 ]
机构
[1] Amirkabir Univ Technol, Tehran Polytech, Dept Min & Met Engn, Tehran, Iran
[2] Sahand Univ Technol, Mat Engn Fac, Tabriz, Iran
[3] Amirkabir Univ Technol, Res Ctr Mat & Min Ind Technol, Tehran, Iran
关键词
Solvent extraction; Palladium; TBP; Chloride media;
D O I
暂无
中图分类号
P5 [地质学];
学科分类号
0709 ; 081803 ;
摘要
In recent years, precious metals production through hydrometallurgical process has been attended; however the Low grade of metals is one of the main problems. Thus, solvent extraction method was purposed for concentration and purification of aqueous solution. In this study, Tri butyl phosphate (TBP) was used to PdCl3 low concentrations of TBP could extract Pd chloride ions. The Solution containing 180 mg/l Pd was extracted by 0.05-0.25 M TBP in different HCl concentration. Increasing HCl concentration decreases Pd extraction percentage. It seems that different chloride complexes formations cause the extraction percentage to change in various HCl concentrations. The extracted macromolecule is determined PdCl3-center dot TBP center dot xHR(2)O center dot HNO3 and NaCl has negative effect on Pd extraction.
引用
收藏
页码:747 / 751
页数:5
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