Styryl dyes as new photoinitiators for free radical polymerization

被引：20
|
作者：
Sokolowska, Jolanta [1 ]
Podsiadly, Radoslaw [1 ]
Stoczkiewicz, Jakub [1 ]
机构：
[1] Tech Univ Lodz, Inst Polymer & Dye Technol, PL-90924 Lodz, Poland
来源：
DYES AND PIGMENTS | 2008年 / 77卷 / 03期
关键词：
photoinitiator; photopolymerization; styryl dyes;
D O I：
10.1016/j.dyepig.2006.11.011
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Several disperse and cationic styryl dyes have been synthesized and evaluated for the initiation of free radical polymerization of ethyl acrylate under UV-vis light. The kinetic study of photoinitiated polymerization performed with the use of suitable electron donors such as ethyl 4-N, N-dimethylaminobenzoate (DMB), phenylthioacetic acid (PhSAc) and phenoxyacetic acid (PhOAc) has proved that tested dyes are good electron acceptors. It has been shown that the intermolecular electron transfer is the limiting step in the photoinitiated polymerization process. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：510 / 514
页数：5
相关论文
共 50 条
  • [41] POLYMERIC AND POLYMERIZABLE FREE-RADICAL PHOTOINITIATORS
    DAVIDSON, RS
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1993, 69 (03) : 263 - 275
  • [42] A new era of free-radical polymerization
    Yamada, B
    TRENDS IN POLYMER SCIENCE, 1996, 4 (11) : 388 - 389
  • [43] NEW PERSPECTIVE IN FREE-RADICAL POLYMERIZATION
    DASS, NN
    MAHATO, PK
    INDIAN JOURNAL OF TECHNOLOGY, 1993, 31 (4-6): : 161 - 171
  • [44] 3-Ketoquinolones as new photoinitiators for free radical photopolymerization under LED
    Morone, Marika
    Postle, Stephen
    Razzano, Vincenzo
    Deguines, Charles
    Allonas, X.
    POLYMER CHEMISTRY, 2022, 13 (18) : 2659 - 2664
  • [45] Flavones as natural photoinitiators for light mediated free-radical polymerization via light emitting diodes
    Al Mousawi, Assi
    Garra, Patxi
    Dumur, Frederic
    Graff, Bernadette
    Fouassier, Jean Pierre
    Lalevee, Jacques
    JOURNAL OF POLYMER SCIENCE, 2020, 58 (02) : 254 - 262
  • [46] PHOTOINITIATORS AND PHOTOINITIATION .9. PHOTOINITIATORS FOR RADICAL POLYMERIZATION WHICH COUNTER OXYGEN-INHIBITION
    HAGEMAN, HJ
    JANSEN, LGJ
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1988, 189 (12): : 2781 - 2795
  • [47] Applicability of hemicyanine phenyltrialkylborate salts as free-radical photoinitiators in the visible-light polymerization of acrylate
    Jedrzejewska, Beata
    Pietrzak, Marek
    JOURNAL OF APPLIED POLYMER SCIENCE, 2012, 123 (06) : 3535 - 3544
  • [48] Perovskites as new radical photoinitiators for radical and cationic polymerizations
    Mokbel, Haifaa
    Dumur, Frederic
    Raveau, Bernard
    Morlet-Savary, Fabrice
    Simonnet-Jegat, Corine
    Gigmes, Didier
    Toufaily, Joumana
    Hamieh, Tayssir
    Fouassier, Jean Pierre
    Lalevee, Jacques
    TETRAHEDRON, 2016, 72 (48) : 7686 - 7690
  • [49] PHOTO-POLYMERIZATION OF N-VINYLCARBAZOLE IN DICHLOROMETHANE IN THE PRESENCE AND ABSENCE OF FREE-RADICAL PHOTOINITIATORS
    TERRELL, DR
    POLYMER, 1982, 23 (07) : 1045 - 1050
  • [50] Conventional Type II photoinitiators as activators for photoinduced metal-free atom transfer radical polymerization
    Allushi, Andrit
    Kutahya, Ceren
    Aydogan, Cansu
    Kreutzer, Johannes
    Yilmaz, Gorkem
    Yagci, Yusuf
    POLYMER CHEMISTRY, 2017, 8 (12) : 1972 - 1977
12345