Synthesis of fluorodihydroxysulfonium hexafluoroantimonate [FS(OH)2]+[SbF6]-

被引：6

作者：

Kornath, A ^{[1
]}

Seelbinder, R ^{[1
]}

Minkwitz, R ^{[1
]}

机构：

[1] Univ Dortmund, Dept Chem, D-44227 Dortmund, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 06期

关键词：

fluorosulfinic acid; Raman spectroscopy; structure elucidation; sulfur dioxide; superacid systems;

D O I：

10.1002/anie.200461847

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Audience participation: Fluorosulfinic acid, which is not known in its free state, was isolated in its protonated form as the [FS(OH)2] +[SbF6]- salt. It was prepared by addition of SO2 to the superacid HF/SbF5. SO2 has been used as a solvent for HF/SbF5 superacid systems for over 40 years. Only now is it shown that when SO2 is added to HF/SbF5 the [FS(OH)2]+ ion (see structure) is formed in an equilibrium with the SO2SbF5 adduct.

引用

页码：973 / 975

页数：3

共 50 条

[21] PREPARATION AND RAMAN-SPECTRA OF TRIBROMOSULFUR(IV) HEXAFLUOROARSENATE(V) AND HEXAFLUOROANTIMONATE(V), (SBR3)+(ASF6)- AND (SBR3)+(SBF6)-
PASSMORE, J
RICHARDSON, EK
TAYLOR, P
INORGANIC CHEMISTRY, 1978, 17 (06) : 1681 - 1683
[22] THE STRUCTURE OF MERCURY HEXAFLUOROANTIMONATE HG3-DELTA-SBF6
TUN, Z
BROWN, ID
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (SEP): : 2321 - 2324
[23] The Platinum(II) Salt Pt(H2O)4(SbF6)2
Seppelt, Konrad
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (13-14): : 2391 - 2393
[24] Synthesis, crystal structure and solid state photoluminescence of [Pt(trpy)(C≡CPh)]SbF6 (trpy=2,2′:6′,2"-terpyridine)
Buchner, Riaan
Field, John S.
Haines, Raymond J.
Ledwaba, Lesibana P.
McGuire, Robert, Jr.
McMillin, David R.
Munro, Orde Q.
INORGANICA CHIMICA ACTA, 2007, 360 (05) : 1633 - 1638
[25] Strong HF hydrogen bonds as synthons in polymeric quantum magnets: Structural, magnetic, and theoretical characterization of [Cu(HF 2)(pyrazine)2]SbF6, [Cu2F(HF) (HF2)(pyrazine)4](SbF6)2, and [CuAg(H3F4)(pyrazine)5](SbF6) 2
Manson, Jamie L.
Schlueter, John A.
Funk, Kylee A.
Southerland, Heather I.
Twamley, Brendan
Lancaster, Tom
Blundell, Stephen J.
Baker, Peter J.
Pratt, Francis L.
Singleton, John
McDonald, Ross D.
Goddard, Paul A.
Sengupta, Pinaki
Batista, Cristian D.
Ding, Letian
Lee, Changhoon
Whangbo, Myung-Hwan
Franke, Isabel
Cox, Susan
Baines, Chris
Trial, Derek
Journal of the American Chemical Society, 2009, 131 (19): : 6733 - 6747
[26] Magnetic ground state of the two isostructual polymeric quantum magnets [Cu(HF2)(pyrazine)2]SbF6 and [Co(HF2)(pyrazine)2]SbF6 investigated with neutron powder diffraction
Brambleby, J.
Goddard, P. A.
Johnson, R. D.
Liu, J.
Kaminski, D.
Ardavan, A.
Steele, A. J.
Blundell, S. J.
Lancaster, T.
Manuel, P.
Baker, P. J.
Singleton, J.
Schwalbe, S. G.
Spurgeon, P. M.
Tran, H. E.
Peterson, P. K.
Corbey, J. F.
Manson, J. L.
PHYSICAL REVIEW B, 2015, 92 (13):
[27] PREPARATION AND CHARACTERIZATION OF SE10(ASF6)2,SE10(SBF6)2, AND SE10(ALCL4)2 AND CRYSTAL-STRUCTURE OF SE10(SBF6)2
BURNS, RC
CHAN, WL
GILLESPIE, RJ
LUK, WC
SAWYER, JF
SLIM, DR
INORGANIC CHEMISTRY, 1980, 19 (06) : 1432 - 1439
[28] Lewis acidity of Ca2+ in Ca(AsF6)2 and Ca(SbF6)2.
Zemva, B
Benkiè, P
Tramsek, M
Turiènik, A
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U550 - U550
[29] CRYSTAL-STRUCTURE OF (MU-P-CHLOROPHENYLSELENOLATO)-BIS(TRIPHENYLPHOSPHINEGOLD(I)) HEXAFLUOROANTIMONATE, CLC6H4SE(AUP(C6H5)3)2(SBF6)
JONES, PG
LAUTNER, J
THONE, C
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1993, 208 : 354 - 357
[30] Crystal Structures of Hydrazinium(II) Salts of [SbF6]- and [Sb2F11]-
Mazej, Zoran
Goreshnik, Evgeny A.
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2015, 641 (07): : 1216 - 1219

← 1 2 3 4 5 →