Synthesis, structures and ethylene polymerization activity of chromium(III) complexes with N,O,N′-tridentate ligands

被引：9
|
作者：
Chen, Fei [1 ]
Lu, Xiang-Yong [1 ]
Chen, Xue-Tai [1 ]
Li, Hua-Yi [2 ]
Hu, You-Liang [2 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China
[2] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Engn Plast, Inst Chem, Beijing 100080, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2012年 / 387卷
关键词：
Chromium; Tridentate ligand; Ethylene; Polymerization; Catalysis; OLEFIN POLYMERIZATION; CRYSTAL-STRUCTURES; HOMOGENEOUS MODEL; PHILLIPS CATALYST; OLIGOMERIZATION; BEHAVIOR; METAL; COPPER(II); CHLORIDES;
D O I：
10.1016/j.ica.2012.02.037
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This paper reports the synthesis and characterization of four neutral chromium(III) complexes bearing N,O,N'-tridentate ligands, [LCrCl3], (L = 2-[(2-pyridylmethoxy)methyl]pyridine, 1; L = 8-(2-pyridylmethoxy) quinoline, 2; L = 8-[(2-pyridylmethoxy)methyl]quinoline, 3; L = 8-(quinolin-8-ylmethoxy)quinoline,4). Molecular structures of 1-3 have been determined by X-ray crystallography, which show that L-1 and L-3 exhibit facial configuration in 1 and 3 while L-2 adopts meridional arrangement in 2. The ethylene polymerization experiments show that complexes 1-4 are moderately active precatalysts for ethylene polymerization with activation with MAO. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：407 / 411
页数：5
相关论文
共 50 条
  • [41] A series of mononuclear Co(III) complexes using tridentate N,O-donor ligands: Chemical properties and cytotoxicity activity
    Souza, Elizabeth Teixeira
    Sousa Maia, Paulo Jose
    Azevedo, Erica Melo
    Kaiser, Carlos Roland
    Lamounier Camargos Resende, Jackson Antonio
    Pinheiro, Carlos Basilio
    Heinrich, Tassiele Andrea
    da Silva, Roberto Santana
    Scarpellini, Marciela
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2011, 105 (12) : 1767 - 1773
  • [42] New Chromium(III) Complexes with Imine-Cyclopentadienyl Ligands: Synthesis, Characterization, and Catalytic Properties for Ethylene Polymerization
    Zhang, Lei
    Gao, Wei
    Tao, Xin
    Wu, Qiaolin
    Mu, Ying
    Ye, Ling
    ORGANOMETALLICS, 2011, 30 (03) : 433 - 440
  • [43] Synthesis and characterization of iron(III), manganese(III) and chromium(III) complexes with N,N′-ethylene-bis(3-carboxypropenamide)
    Namboori, CGR
    Krishnan, G
    ASIAN JOURNAL OF CHEMISTRY, 2004, 16 (3-4) : 1455 - 1462
  • [44] Ethylene oligomerization promoted by chromium complexes bearing imine tridentate ligands
    Pinheiro, Adriana
    Bergamo, Adao
    Casagrande, Adriana
    Kirillov, Evgueni
    Carpentier, Jean-Francois
    Casagrande, Osvaldo
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [45] Synthesis, characterization and antimicrobial activity of nickel(II) complexes of tridentate N3 ligands
    Das, Athulya
    Rajeev, Anjana
    Bhunia, Sarmistha
    Arunkumar, Manivel
    Chari, Nithya
    Sankaralingam, Muniyandi
    INORGANICA CHIMICA ACTA, 2021, 526
  • [46] Synthesis, structures and ethylene polymerization behavior of half-metallocene chromium(III) catalysts bearing salicylaldiminato ligands
    Sun, Mingtai
    Mu, Ying
    Wu, Qiaolin
    Gao, Wei
    Ye, Ling
    NEW JOURNAL OF CHEMISTRY, 2010, 34 (12) : 2979 - 2987
  • [47] Magnesium and Zinc Complexes Supported by N,N,O Tridentate Ligands: Synthesis and Catalysis in the Ring-Opening Polymerization of rac-Lactide and α-Methyltrimethylene Carbonate
    Huang, Miao
    Ma, Haiyan
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (23) : 3791 - 3803
  • [48] New Half-Sandwich Chromium(III) Complexes Bearing Phenoxy-Phosphine (Oxide) [O,P(=O)] Ligands: Synthesis, Structures, and Catalytic Properties for Ethylene (Co)Polymerization
    Tao, Ping
    Mu, Hong-Liang
    Liu, Jing-Yu
    Li, Yue-Sheng
    ORGANOMETALLICS, 2013, 32 (17) : 4805 - 4812
  • [49] Synthesis of [O, O, N, O] Ligands for Application in Polymerization
    Myers, Kristina
    Anderson-Wile, Amelia
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [50] New chromium complexes for ethylene oligomerization: Extended use of tridentate ligands in metal-catalyzed olefin polymerization
    Small, BL
    Carney, MJ
    Holman, DM
    O'Rourke, CE
    Halfen, JA
    MACROMOLECULES, 2004, 37 (12) : 4375 - 4386
12345