Synthesis of 2,6-disubstituted tetrahydroazulene derivatives

被引：1

作者：

Hussain, Zakir ^{[1
,2
]}

Hopf, Henning ^{[1
]}

Ayub, Khurshid ^{[2
]}

Eichhorn, S. Holger ^{[3
]}

机构：

[1] Tech Univ Carolo Wilhelmina Braunschweig, Inst Organ Chem, D-38106 Braunschweig, Germany

[2] COMSATS Inst Informat Technol CIIT, Dept Chem, Abbottabad 22060, KPK, Pakistan

[3] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 8卷

关键词：

carbene addition; hydroazulenes; liquid crystals; ring expansion;

D O I：

10.3762/bjoc.8.77

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Synthesis of hydroazulene derivatives has been carried out through a ring-enlargement route by using carbene adduct intermediates. The protocol can be applied for the construction of functionalized hydroazulene skeletons as key components of many natural products as well as the core system of novel liquid-crystalline materials.

引用

页码：693 / 698

页数：6

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