Flexible and Conductive 3D Printable Polyvinylidene Fluoride and Poly(N,N-dimethylacrylamide) Based Gel Polymer Electrolytes

被引：18
|
作者：
Rahman, Md Sazzadur [1 ]
Shiblee, M. D. Nahin Islam [1 ]
Ahmed, Kumkum [2 ]
Khosla, Ajit [1 ]
Ogawa, Jun [1 ]
Kawakami, Masaru [1 ]
Furukawa, Hidemitsu [1 ]
机构：
[1] Yamagata Univ, Grad Sch Sci & Engn, Dept Mech Syst Engn, Soft & Wet Matter Engn Lab SWEL, 4-3-16 Jonan, Yonezawa, Yamagata 9928510, Japan
[2] Shibaura Inst Technol, Coll Engn, 3 Chome 7-5 Toyosu, Koto City, Tokyo 1358548, Japan
来源：
MACROMOLECULAR MATERIALS AND ENGINEERING | 2020年 / 305卷 / 09期
基金：
日本科学技术振兴机构; 日本学术振兴会;
关键词：
3D printing; crosslinked gels; flexible; gel polymer electrolyte; ionic conductivity; BATTERY;
D O I：
10.1002/mame.202000262
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
In this work, 3D printable gel polymer electrolytes (GPEs) based onN,N-dimethylacrylamide (DMAAm) and polyvinylidene fluoride (PVDF) in lithium chloride containing ethylene glycol solution are synthesized and their physicochemical properties are investigated. 3D printing is carried out with a customized stereolithography type 3D gel printer named "Soft and Wet Intelligent Matter-Easy Realizer" and free forming GPE samples having variable shapes and sizes are obtained. Printed PVDF/PDMAAm-based GPEs exhibit tunable mechanical properties and favorable thermal stability. Electrochemical proprieties of the printed GPEs are carried out via impedance spectroscopy in the temperature range of 25-90 degrees C by varying PVDF content. Ionic conductivity as high as 6.5 x 10(-4)S cm(-1)is achieved at room temperature for GPE containing low PVDF content (5 wt%) and conductivity of the GPEs is increased as temperature rises.
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页数：8
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