We have developed an approach for gamma-ray optics using layered structures acting as planar waveguides. Experiments demonstrating channeling of 122 keV gamma rays in two prototype waveguides validate the feasibility of this technology. Gamma-ray waveguides allow one to control the direction of radiation up to a few MeV. The waveguides are conceptually similar to polycapillary optics, but can function at higher gamma-ray energies. Optics comprised of these waveguides will be able to collect radiation from small solid angles or concentrate radiation into small area detectors. Gamma-ray waveguides may find applications in medical imaging and treatment, astrophysics, and homeland security. (c) 2008 American Institute of Physics.