Sunlight-induced decarboxylative radical addition of carboxylic acids to electron-deficient alkenes using a millitube reactor

被引：7

作者：

Yoshimi, Yasuharu ^{[1
]}

Nishio, Akinori ^{[1
]}

Hayashi, Masae ^{[1
]}

Morita, Toshio ^{[1
]}

机构：

[1] Univ Fukui, Grad Sch Engn, Dept Appl Chem & Biotechnol, 3-9-1 Bunkyo, Fukui 9108507, Japan

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2016年 / 331卷

关键词：

Sunlight-induced; Decarboxylative radical addition; Electron-deficient alkene; Millitube reactor; PHOTOCHEMICAL DECARBOXYLATION; 2+2 PHOTOCYCLOADDITION; PHOTOREDOX CATALYSIS; GREEN PHOTOCHEMISTRY; RING EXPANSION; COMPLEXES; ROUTE;

D O I：

10.1016/j.jphotochem.2016.03.012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The use of a fluorinated ethylene propylene (FEP) millitube reactor significantly improved the efficiency of the photoinduced decarboxylative radical addition of aliphatic carboxylic acids to electron-deficient alkenes, producing the corresponding gamma-amino acid derivative and macrocyclic lactone. These sunlight-induced photoreactions were achieved using a millitube reactor, even though the photosensitizer used in this system absorbs only UV light. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：17 / 21

页数：5