Coordination Structure of Bi atoms in Li2O-Bi2O3-B2O3 Glasses by X-ray Diffraction

被引：4

作者：

Fukumi, Kohei ^{[1
]}

Kitamura, Naoyuki ^{[1
]}

Kozuka, Hiromitsu ^{[2
]}

Kohara, Shinji ^{[3
]}

机构：

[1] Natl Inst Advance Ind Sci & Technol, Inorgan Funct Mat Res Inst, 1-8-31 Midorigaoka, Ikeda, Osaka 5638577, Japan

[2] Kansai Univ, Fac Chem Mat & Bioengn, Dept Chem & Mat Engn, 3-3-35 Yamate Cho, Suita, Osaka 5648680, Japan

[3] Natl Inst Mat Sci, Adv Key Technol Div, 1-1-1 Kouto, Sayo, Hyogo 6795148, Japan

来源：

JOURNAL OF THE CERAMIC SOCIETY OF JAPAN | 2018年 / 126卷 / 12期

关键词：

Glass structure; Li2O-Bi2O3-B2O3; Bi atoms; X-ray diffraction; CRYSTAL-STRUCTURE; OPTICAL-PROPERTIES; BISMUTH BORATE; PHOSPHATE; BASICITY; NEUTRON; PATTERN;

D O I：

10.2109/jcersj2.18112

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The coordination structure around Bi atoms has been studied in Li2O-Bi2O3-B2O3 glasses by X-ray diffraction method. It was found that Bi atoms were coordinated by five or six oxygen atoms. The number of Bi atoms around a Bi atom through Bi-O-Bi bonds increased with an increase in Bi/O ratio. It was inferred that BiOx polyhedra were clumped in the glasses, although BiOx polyhedra were more clumped in Li2O-Bi2O3-B2O3 glasses than in Bi2O3-B2O3 glasses. (C) 2018 The Ceramic Society of Japan. All rights reserved.

引用

页码：992 / 996

页数：5

共 50 条

[41] Structural investigations of gamma-irradiated glasses of the systems Bi2O3.B2O3 and Bi2O3.B2O3.PbO
El-Batal, HA
Azooz, MA
Ezz-El-Din, FM
APPLIED MINERALOGY, VOLS 1 AND 2: RESEARCH, ECONOMY, TECHNOLOGY, ECOLOGY AND CULTURE, 2000, : 131 - 134
[42] VARIATION OF PROPERTIES OF GLASSES ALONG THE 3BI2O3.5B2O3-4PBO.B2O3 AND PBO.2B2O3-2PBO.BI2O3 SECTIONS OF THE PBO-BI2O3-B2O3 TERNARY-SYSTEM
ZARGAROVA, MI
SHUSTER, NS
INORGANIC MATERIALS, 1985, 21 (02) : 223 - 227
[43] Thermal expansion and infrared studies of binary Bi2O3-B2O3 and ternary Bi2O3-B2O3-PbO glasses
El-Batal, FH
Azooz, MA
Ezz-Eldin, FM
PHYSICS AND CHEMISTRY OF GLASSES, 2002, 43 (05): : 260 - 266
[44] Study of structure and Li+ ions dynamics in presence of Fe2O3 in Bi2O3·B2O3 glasses
Rani S.
Sanghi S.
Agarwal A.
Kishore N.
Solid State Phenomena, 2010, 161 : 51 - 61
[45] 209Bi NQR in Mixed Oxides 2Bi2O3· B2O3, 3Bi2O3· 5B2O3, and Bi2O3· 3B2O3
E. A. Kravchenko
Yu. F. Kargin
A. V. Egorysheva
Yu. A. Buslaev
Russian Journal of Coordination Chemistry, 2001, 27 : 542 - 547
[46] 209Bi NQR in mixed oxides 2Bi2O3 • B2O3, 3Bi2O3 • 5B2O3, and Bi2O3 • 3B2O3
Kravchenko, EA
Kargin, YF
Egorysheva, AV
Buslaev, YA
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2001, 27 (08) : 542 - 547
[47] Structure and nonlinear optical properties of PbO-Bi2O3-B2O3 glasses
Terashima, K
Shimoto, TH
Yoko, T
PHYSICS AND CHEMISTRY OF GLASSES, 1997, 38 (04): : 211 - 217
[48] DIELECTRIC PROPERTIES OF GLASSES IN THE SYSTEMS BI2O3-CDO-SIO2, BI2O3-CDO-B2O3, AND BI2O3-CDO-GEO2 AND THEIR RELATION TO THE STRUCTURE OF GLASS
RAO, BVJ
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1962, 45 (11) : 555 - 563
[49] Study on the structure of Bi2O3-Li2O glass
Chen, DP
Jiang, XW
Zhu, CS
JOURNAL OF INORGANIC MATERIALS, 2002, 17 (02) : 202 - 209
[50] PHASE-EQUILIBRIA IN 3BI2O3.8PBO.7B2O3-2BI2O3.B2O3(BI2O3) SYSTEMS
ZARGAROVA, MI
SHUSTER, NS
AFUZOVA, AO
ZHURNAL NEORGANICHESKOI KHIMII, 1987, 32 (08): : 2014 - 2017

← 1 2 3 4 5 →