Iron(III) trifluoroacetate [Fe(O2CCF3)3] catalyzed epoxide opening with amines

被引：15

作者：

Erturk, Erkan ^{[1
]}

Demir, Ayhan S. ^{[1
]}

机构：

[1] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey

来源：

ARKIVOC | 2008年

关键词：

epoxide; epoxide opening; amino alcohol; iron; solvent-free; green chemistry;

D O I：

10.3998/ark.5550190.0009.218

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Non-hygroscopic, non-toxic, and readily available iron(III) trifluoroacetate [Fe(O2CCF3)(3)] was found to be a highly regioselective catalyst for the ring opening of a wide variety of epoxides with diverse amines under solvent-free conditions. The stereospecific ring opening of (R)-styrene oxide (4) with p-anisidine (2b) in the presence of 1 mol% of Fe(O2CCF3)(3) gave 2-(p-methoxyphenyl-amino)-2-phenylethanol (5b) in enantiopure form (> 99 % ee) within 60 minutes.

引用

页码：160 / 171

页数：12

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