Cycloheptatrienyl, alkyl and aryl PCP-pincer complexes: Ligand backbone effects and metal reactivity

被引：148
|
作者：
Leis, Wolfgang [1 ]
Mayer, Hermann A. [1 ]
Kaska, William C. [2 ]
机构：
[1] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany
[2] Univ Calif Santa Barbara, Dept Chem, Santa Barbara, CA 93106 USA
来源：
COORDINATION CHEMISTRY REVIEWS | 2008年 / 252卷 / 15-17期
基金：
美国国家科学基金会;
关键词：
PCP-pincer ligands; C-H activation; N-H activation; CO2; activation; hydrides;
D O I：
10.1016/j.ccr.2008.02.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Pincer complexes have developed into a class of compounds with a tremendous breadth of applications in organometallic chemistry and catalysis. In this article we have selected a few PCP-pincer ligand systems and demonstrate that small changes in the ligand backbone have a dramatic impact on the reactivity change of their metal complexes. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：1787 / 1797
页数：11
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