Cross-metathesis of unsaturated natural oils with 2-butene. High conversion and productive catalyst turnovers

被引：56
|
作者：
Patel, J
Elaridi, J
Jackson, WR
Robinson, AJ
Serelis, AK
Such, C
机构：
[1] Monash Univ, Sch Med, Ctr Green Chem, Clayton, Vic 3800, Australia
[2] Dulux Australia Technol, Clayton, Vic 3168, Australia
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 44期
关键词：
D O I：
10.1039/b511626k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
ne cross-metathesis of synthetic and natural triglycerides containing unsaturated fatty acids with 2-butene can be achieved with high conversion and excellent productive turnovers. These reactions are catalysed by second-generation ruthenium-based olefin metathesis catalysts and can be conducted at -5 degrees C in liquid 2-butene.
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页码：5546 / 5547
页数：2
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