A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

被引：77
|
作者：
Luca, Oana R. [1 ]
Konezny, Steven J. [1 ]
Blakemore, James D. [1 ]
Colosi, Dominic M. [2 ]
Saha, Shubhro [1 ]
Brudvig, Gary W. [1 ]
Batista, Victor S. [1 ]
Crabtree, Robert H. [1 ]
机构：
[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA
[2] Yale Univ, Dept Geol & Geophys, Earth Syst Ctr Stable Isotop Studies, New Haven, CT 06511 USA
来源：
NEW JOURNAL OF CHEMISTRY | 2012年 / 36卷 / 05期
关键词：
COUPLED ELECTRON-TRANSFER; FUNCTIONAL MODELS; COBALT; COMPLEXES; EVOLUTION; REDUCTION; WATER; ELECTROCHEMISTRY; PROTONS; CYCLOADDITION;
D O I：
10.1039/c2nj20912h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Ni-II complex with a redox-active pincer ligand reduces protons at a low overpotential in aqueous acidic conditions. A combined experimental and computational study provides mechanistic insights into a putative catalytic cycle.
引用
收藏
页码：1149 / 1152
页数：4
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