Hydrothermal Synthesis and Crystal Structure of a Nickel(II) Polymer with a One-dimensional Chain Structure: [Ni(cbba)2(bipy)(H2O)2]n

被引：0
|
作者：
Li Xiu-Mei [1 ]
Wang Qing-Wei [2 ]
Wang Zhi-Tao [1 ]
Liu Bo [2 ]
机构：
[1] Tonghua Teachers Coll, Dept Chem, Tonghua 134002, Jilin, Peoples R China
[2] Jilin Normal Univ, Siping 136000, Jilin, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2011年 / 30卷 / 02期
关键词：
hydrothermal synthesis; crystal structure; coordination polymer; COMPLEXES; DESIGN;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A metal-organic coordination polymer formulated as [Ni(cbba)(2)(bipy)(H2O)(2)](n) 1 (H(2)cbba = 2-(4'-chlorine-benzoyl)benzoic acid, bipy = 4,4'-bipyridine) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. The title compound crystallizes in the triclinic system, space group P (1) over bar with a = 5.4550(4), b = 11.4099(8), c = 15.3135(11) angstrom, alpha = 68.7680(10), beta = 81.3470(10), gamma = 79.3450(10)degrees, V = 869.48(11) angstrom(3), C38H28Cl2N2NiO8, M-r = 770.23, D-c = 1.471 g/cm(3), mu(MoK alpha) = 0.768 mm(-1), F(000) = 396, Z = 1, the final R = 0.0456 and wR = 0.1171 for 2477 observed reflections (I > 2 sigma(I)). It exhibits a one-dimensional chain-like structure.
引用
收藏
页码：176 / 179
页数：4
相关论文
共 50 条
  • [31] Synthesis, crystal structure and luminescent property of a novel H2O-bridged cobalt(II) polymer with one-dimensional chain structure
    Yang, En-Cui
    Dai, Pei-Xia
    Wang, Xiu-Guang
    Zhao, Xiao-Jun
    TRANSITION METAL CHEMISTRY, 2007, 32 (02) : 228 - 232
  • [32] Synthesis, crystal structure and luminescent property of a novel H2O-bridged cobalt(II) polymer with one-dimensional chain structure
    En-Cui Yang
    Pei-Xia Dai
    Xiu-Guang Wang
    Xiao-Jun Zhao
    Transition Metal Chemistry, 2007, 32 : 228 - 232
  • [33] Synthesis, crystal structure and electrochemical properties of a one-dimensional chain coordination polymer [Cu(phen)(2,4,6-TMBA)2(H2O)]n
    Li Wei
    Li Chang-Hong
    Yang Ying-Qun
    Kuang Yun-Fei
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 27 (02) : 210 - 214
  • [34] Synthesis and crystal structure of one-dimensional chain coordination polymer [Mn(9-AC)2(4,4′-bpy) (H2O)2]n
    Zhao Guo-Li
    Wu Ying
    Ye Jun-Wei
    Ye Kai-Qi
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2008, 29 (04): : 686 - 689
  • [35] Synthesis, Crystal Structure and Electrochemical Properties of a One-dimensional Chain Coordination Polymer [Mn（phen）(2,4,6-TMBA)2（H2O）]n
    杨颖群
    李昶红
    李薇
    匡云飞
    Chinese Journal of Structural Chemistry, 2007, (09) : 1076 - 1080
  • [36] Synthesis and Crystal Structure of One-dimensional Chain Zinc（II） Coordination Polymer: {Na[ZnL（H2O）2]}n （L =2-Hydroxyl-2-hydroxylate-malonate Trivalent Anion）
    SHI Jing-Min② ZHU Si-Cheng WU Chang-Ju (Department of Chemistry
    结构化学, 2004, (09) : 1027 - 1029
  • [37] Synthesis and crystal structure of one-dimensional chain zinc(II) coordination polymer:: {Na[ZnL(H2O)2]}n (L=2-hydroxyl-2-hydroxylate-malonate trivalent anion)
    Shi, JM
    Zhu, SC
    Wu, CJ
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (09) : 1027 - 1029
  • [38] Hydrothermal synthesis and crystal structure of a novel coordination polymer [Co(pda)2(H2O)2]n
    Zhou, Qiu-Xiang
    Bai, Xiao-Jie
    Chen, Le-Pei
    Rengong Jingti Xuebao/Journal of Synthetic Crystals, 2006, 35 (01): : 197 - 200
  • [39] Synthesis and crystal structure of a new one-dimensional double helical-chain polymer, {Zn(O2CC12H8CO2)(H2O)}n
    Yin, PX
    Zhang, J
    Wen, YH
    Cheng, JK
    Li, ZJ
    Yao, YG
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (10) : 1107 - 1110
  • [40] Synthesis and crystal structure of one-dimensional chainlike coordination polymer [Ag(bix)(NO3)(H2O)]n
    Wu, YP
    Wen, LL
    Li, YZ
    Dang, DB
    Lu, ZD
    Meng, QJ
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2005, 21 (11) : 1759 - 1762
12345