Synthesis of N-heterocyclic compounds via ene-yne metathesis reactions

被引：24

作者：

Groaz, Elisabetta ^{[1
]}

Banti, Donatella ^{[1
,2
]}

North, Michael ^{[1
,3
]}

机构：

[1] Kings Coll London, Dept Chem, London WC2R 2LS, England

[2] Kingston Univ, Sch Pharm & Chem, Kingston upon Thames KT1 2EE, Surrey, England

[3] Univ Newcastle, Sch Nat Sci, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

TETRAHEDRON | 2008年 / 64卷 / 01期

关键词：

nitrogen heterocycles; ring closing; enyne; metathesis; ruthenium;

D O I：

10.1016/j.tet.2007.10.076

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Propargylamino and allylamino derivatives of cyclohexene and norbornene were subjected to tandem metathesis reactions with first and second generation Grubbs' catalysts 1 and 2. Results show that the method is compatible with suitably protected nitrogen-containing compounds. Cyclohexenes gave intriguing results in terms of the possibility to perform ring rearrangement metathesis (RRM) reactions, showing a difference with the analogous allyl and propargyl ether substrates. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：204 / 218

页数：15

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