Self-assembly of mixed-valent ruthenium(II,III) pivalate and octacyanotungstate(V) building blocks

被引：27
|
作者：
Matoga, D
Mikuriya, M
Handa, M
Szklarzewicz, J
机构：
[1] Kwansei Gakuin Univ, Sch Sci & Technol, Dept Chem, Sanda 6691337, Japan
[2] Kwansei Gakuin Univ, Sch Sci & Technol, Open Res Ctr Coordinat Mol Based Devices, Sanda 6691337, Japan
[3] Shimane Univ, Interdisciplinary Fac Sci & Engn, Dept Mat Sci, Matsue, Shimane 6908504, Japan
[4] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland
来源：
CHEMISTRY LETTERS | 2005年 / 34卷 / 11期
关键词：
D O I：
10.1246/cl.2005.1550
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
One-dimensional coordination polymer of [Ru-2(piv)(4)(mu-CN)W(CN)7](n)(2n-) (Hpiv = pivalic acid) has been synthesized in the presence of PPh4+. The X-ray crystal structure reveals an alternating arrangement of ruthenium(II,III) dimers and [W(CN)(8)](3-) ions in a 1-D chain. The magnetic susceptibility data (4.5-300 K) shows a ferrimagnetic behavior of this complex.
引用
收藏
页码：1550 / 1551
页数：2
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