Polystannanes: Polymers of a molecular, jacketed metal-wire structure

被引：23

作者：

Choffat, Fabien ^{[1
]}

Smith, Paul ^{[1
]}

Caseri, Walter ^{[1
]}

机构：

[1] ETH, CH-8093 Zurich, Switzerland

来源：

ADVANCED MATERIALS | 2008年 / 20卷 / 11期

关键词：

D O I：

10.1002/adma.200702268

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polystannanes, organometallic polymers with a backbone of covalently connected tin atoms, can be regarded as molecular metal wires surrounded by a jacket of organic matter (see figure). Polymers that differ in the length of the alkyl side groups feature reversible phase transitions into liquid-crystalline states (some of them even below room temperature) and are oriented either parallel or perpendicular to external driving forces, depending on the length of the alkyl substituents.

引用

页码：2225 / +

页数：6

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