Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker

被引：45
|
作者：
Clingerman, Daniel J. [1 ,2 ]
Morris, William [1 ,2 ]
Mondloch, Joseph E. [1 ,2 ]
Kennedy, Robert D. [1 ,2 ]
Sarjeant, Amy A. [1 ,2 ]
Stern, Charlotte [1 ,2 ]
Hupp, Joseph T. [1 ,2 ]
Farha, Omar K. [1 ,2 ,3 ]
Mirkin, Chad A. [1 ,2 ]
机构：
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[2] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA
[3] Fac Sci, Dept Chem, Jeddah 22254, Saudi Arabia
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 30期
基金：
美国国家科学基金会;
关键词：
GAS-STORAGE; SEPARATION; ADSORPTION;
D O I：
10.1039/c4cc09212k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first tritopic carborane-based linker, H(3)BCA (C15B24O6H30), based on closo-1,10-C2B8H10, has been synthesized and incorporated into a metal-organic framework (MOF), NU-700 (Cu-3(BCA)(2)). In contrast to the analogous MOF-143, NU-700 can be activated with retention of porosity, yielding a BET surface area of 1870 m(2) g(-1).
引用
收藏
页码：6521 / 6523
页数：3
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