Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker

被引：45
|
作者：
Clingerman, Daniel J. [1 ,2 ]
Morris, William [1 ,2 ]
Mondloch, Joseph E. [1 ,2 ]
Kennedy, Robert D. [1 ,2 ]
Sarjeant, Amy A. [1 ,2 ]
Stern, Charlotte [1 ,2 ]
Hupp, Joseph T. [1 ,2 ]
Farha, Omar K. [1 ,2 ,3 ]
Mirkin, Chad A. [1 ,2 ]
机构：
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[2] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA
[3] Fac Sci, Dept Chem, Jeddah 22254, Saudi Arabia
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 30期
基金：
美国国家科学基金会;
关键词：
GAS-STORAGE; SEPARATION; ADSORPTION;
D O I：
10.1039/c4cc09212k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first tritopic carborane-based linker, H(3)BCA (C15B24O6H30), based on closo-1,10-C2B8H10, has been synthesized and incorporated into a metal-organic framework (MOF), NU-700 (Cu-3(BCA)(2)). In contrast to the analogous MOF-143, NU-700 can be activated with retention of porosity, yielding a BET surface area of 1870 m(2) g(-1).
引用
收藏
页码：6521 / 6523
页数：3
相关论文
共 50 条
  • [1] Carborane-Based Metal-Organic Framework with High Methane and Hydrogen Storage Capacities
    Kennedy, Robert D.
    Krungleviciute, Vaiva
    Clingerman, Daniel J.
    Mondloch, Joseph E.
    Peng, Yang
    Wilmer, Christopher E.
    Sarjeant, Amy A.
    Snurr, Randall Q.
    Hupp, Joseph T.
    Yildirim, Taner
    Farha, Omar K.
    Mirkin, Chad A.
    CHEMISTRY OF MATERIALS, 2013, 25 (17) : 3539 - 3543
  • [2] Robust Carborane-Based Metal-Organic Frameworks for Hexane Separation
    Idrees, Karam B.
    Kirlikovali, Kent O.
    Setter, Caitlin
    Xie, Haomiao
    Brand, Helen
    Lal, Bhajan
    Sha, Fanrui
    Smoljan, Courtney S.
    Wang, Xiaoliang
    Islamoglu, Timur
    Macreadie, Lauren K.
    Farha, Omar K.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (43) : 23433 - 23441
  • [3] Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane
    Bae, Youn-Sang
    Farha, Omar K.
    Spokoyny, Alexander M.
    Mirkin, Chad A.
    Hupp, Joseph T.
    Snurr, Randall Q.
    CHEMICAL COMMUNICATIONS, 2008, (35) : 4135 - 4137
  • [4] A Metal-Organic Framework with a Covalently Prefabricated Porous Organic Linker
    Swamy, Shashikala I.
    Bacsa, John
    Jones, James T. A.
    Stylianou, Kyriakos C.
    Steiner, Alexander
    Ritchie, Lyndsey K.
    Hasell, Tom
    Gould, Jamie A.
    Laybourn, Andrea
    Khimyak, Yaroslav Z.
    Adams, Dave J.
    Rosseinsky, Matthew J.
    Cooper, Andrew I.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (37) : 12773 - 12775
  • [5] A Highly Porous Interpenetrated Metal-Organic Framework from the Use of a Novel Nanosized Organic Linker
    Manos, Manolis J.
    Markoulides, Marios S.
    Malliakas, Christos D.
    Papaefstathiou, Giannis S.
    Chronakis, Nikos
    Kanatzidis, Mercouri G.
    Trikalitis, Pantelis N.
    Tasiopoulos, Anastasios J.
    INORGANIC CHEMISTRY, 2011, 50 (22) : 11297 - 11299
  • [6] Adsorptive Separation of CO2 by a Hydrophobic Carborane-Based Metal-Organic Framework under Humid Conditions
    Gan, Lei
    Andres-Garcia, Eduardo
    Espallargas, Guillermo Minguez
    Planas, Jose Giner
    ACS APPLIED MATERIALS & INTERFACES, 2023, 15 (04) : 5309 - 5316
  • [7] Sterically Invariant Carborane-Based Ligands for the Morphological and Electronic Control of Metal-Organic Chalcogenolate Assemblies
    Mills, Harrison A.
    Jones, Christopher G.
    Anderson, Kierstyn P.
    Ready, Austin D.
    Djurovich, Peter I.
    Khan, Saeed I.
    Hohman, J. Nathan
    Nelson, Hosea M.
    Spokoyny, Alexander M.
    CHEMISTRY OF MATERIALS, 2022, 34 (15) : 6933 - 6943
  • [8] Magnetic properties and magnetocaloric effect of Ln = Dy, Tb carborane-based metal-organic frameworks
    Li, Zhen
    Arauzo, Ana
    Giner Planas, Jose
    Bartolome, Elena
    DALTON TRANSACTIONS, 2024, 53 (21) : 8969 - 8979
  • [9] Highly Porous Metal-Organic Framework Containing a Novel Organosilicon Linker - A Promising Material for Hydrogen Storage
    Wenzel, Stephanie E.
    Fischer, Michael
    Hoffmann, Frank
    Froeba, Michael
    INORGANIC CHEMISTRY, 2009, 48 (14) : 6559 - 6565
  • [10] Formation of a Polythreaded, Metal-Organic Framework Utilizing an Interlocked Hexadentate, Carboxylate Linker
    Gholami, Ghazale
    Zhu, Kelong
    Ward, Jas S.
    Kruger, Paul E.
    Loeb, Stephen J.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (27) : 4524 - 4529
12345