The substituent effects of tert-butyl radical addition to 2-substituted allyl chlorides

被引：6
|
作者：
Wu, YW
机构：
[1] Chemical Engineering Department, Kaohsiung Polytechnic Institute, Ta-Hsu, Kaohsiung
来源：
JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 1996年 / 43卷 / 06期
关键词：
D O I：
10.1002/jccs.199600075
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The relative rates for the addition reactions of tert-butyl radical to 2-substituted allyl chlorides 1 have been determined. The correlation of log k/k(0), vs. sigma(m) gives a rho value of 3.59 with correlation coefficient of 0.930. When the substituent CH2Cl is excluded, correlation coefficient raises to 0.990 and rho value becomes 3.39. The large rho value and the deviation of relative rate of substituent CH2Cl are discussed.
引用
收藏
页码：507 / 509
页数：3
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