Iron Dihydride Complex as the Pre-catalyst for Efficient Hydrosilylation of Aldehydes and Ketones Under Visible Light Activation

被引：83

作者：

Castro, Luis C. Misal ^{[1
]}

Bezier, David ^{[1
]}

Sortais, Jean-Baptiste ^{[1
]}

Darcel, Christophe ^{[1
]}

机构：

[1] Univ Rennes 1, CNRS, UMR Sci Chim Rennes 6226, Equipe Catalyse & Organometall, F-35042 Rennes, France

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2011年 / 353卷 / 08期

关键词：

aldehydes; hydrosilylation; iron catalysis; ketones; reduction; ASYMMETRIC TRANSFER HYDROGENATION; CROSS-COUPLING REACTIONS; C-H; ENANTIOSELECTIVE HYDROSILYLATION; ORGANIC-SYNTHESIS; LIGANDS; POLYMETHYLHYDROSILOXANE; PHOTOCHEMISTRY; ACETOPHENONE; COORDINATION;

D O I：

10.1002/adsc.201000676

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A general and efficient hydrosilylation of aldehydes and ketones into the corresponding alcohols using the well-defined bis(diphenylphosphino-ethane) iron dihydride complex as the pre-catalyst is reported using polymethylhydrosiloxane (PMHS) as the reducing silylating agent and sodium tetraethoxyborate [NaB(OEt)(4)] as a co-catalyst under visible light irradiation. The low catalyst loadings (0.1-1 mol%), the amount of economical hydride source, PMHS and the unconventional way of activation of the pre-catalyst make this new approach attractive.

引用

页码：1279 / 1284

页数：6

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