Topotactic insertion of lithium in the layered structure Li4VO(PO4)2:: The tunnel structure Li5VO(PO4)2

被引：11
|
作者：
Kishore, M. Satya [1 ]
Pralong, V. [1 ]
CaIgnaert, V. [1 ]
Malo, S. [1 ]
Hebert, S. [1 ]
Varadaraju, U. V. [2 ]
Raveau, B. [1 ]
机构：
[1] Univ Caen, CNRS, ENSICAEN, Lab Cristallog & Sci Mat, F-14050 Caen 4, France
[2] Indian Inst Technol Madras, Math Sci Res Ctr, Madras 6000036, Tamil Nadu, India
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2008年 / 181卷 / 04期
关键词：
Li5VO(PO4)(2); intercalation; Li-ion battery; TEM; vanadium phosphate;
D O I：
10.1016/j.jssc.2008.01.044
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new V(III) lithium phosphate Li5VO(PO4)(2) has been synthesized by electrochemical insertion of lithium into Li4VO(PO4)(2). This phase, which crystallizes in the space group I4/mcm, exhibits a tunnel structure closely related to the layered structure of Li4VO(PO4)(2) and to the tunnel structure of VO(H2PO4)(2). The topotactic reactions that take place during lithium exchange and intercalation, starting from VO(H2PO4)(2) and going to the final phase Li5VO(PO4)(2) are explained on the basis of the flexible coordinations of V4+ and V3+ species. The electrochemical and magnetic properties of this new phase are also presented and explained on the basis of the structure dimensionality. (c) 2008 Published by Elsevier Inc.
引用
收藏
页码：976 / 982
页数：7
相关论文
共 50 条
  • [21] The first vanadium aluminophosphates: Hydrothermal synthesis and structure of Cs[(VO)Al(PO4)(2)]center dot H2O, Rb[(VO)Al(PO4)(2)]center dot H2O, (NH3CH2CH2NH2)[(VO)Al(PO4)(2)], and CH3NH3[(VO)Al(PO4)(2)]
    Meyer, LM
    Haushalter, RC
    Zubieta, J
    JOURNAL OF SOLID STATE CHEMISTRY, 1996, 125 (02) : 200 - 210
  • [22] CRYSTAL-STRUCTURE OF LI3IN2(PO4)3
    GENKINA, EA
    MURADYAN, LA
    MAXIMOV, BA
    MERINOV, BV
    SIGAREV, SE
    KRISTALLOGRAFIYA, 1987, 32 (01): : 74 - 78
  • [23] The first vanadium gallophosphates:: Hydrothermal synthesis and structure of Rb[(VO)(H2O)Ga(PO4)2] and Cs[(VO)(H2O)Ga(PO4)2]
    Hammond, RP
    Zubieta, JA
    JOURNAL OF SOLID STATE CHEMISTRY, 1999, 144 (02) : 442 - 448
  • [24] beta-K(VO2)(2)(PO4)
    Yahmed, Safa Ezzine
    Ayed, Meriem
    Zid, Mohamed Faouzi
    Driss, Ahmed
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : I2 - +
  • [25] IONIC-CONDUCTIVITY OF THE LITHIUM TITANIUM PHOSPHATE (LI1+XALXTI2-X(PO4)3), (LI1+XSCXTI2-X(PO4)3), (LI1+XYXTI2-X(PO4)3), (LI1+XLAXTI2-X(PO4)3 SYSTEMS
    AONO, H
    SUGIMOTO, E
    SADAOKA, Y
    IMANAKA, N
    ADACHI, GY
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (02) : 590 - 591
  • [26] The first vanadium gallophosphates:: Hydrothermal synthesis and structure of Rb[(VO)Ga(PO4)2]•H2O and Cs[(VO)Ga(PO4)2]•H2O.
    Hammond, RP
    Zubieta, JA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U146 - U146
  • [27] Facile Synthesis of hybrid phase Li2NaV2(PO4)3 and its application in lithium ion full cell: Li2NaV2(PO4)3∥ Li2NaV2(PO4)3
    Mao, Wen-feng
    Ma, Ye
    Liu, Shan-ke
    Tang, Zhi-yuan
    Fu, Yan-bao
    ELECTROCHIMICA ACTA, 2014, 147 : 498 - 505
  • [28] CRYSTALLINE-STRUCTURE OF LI(FE, ZN)[PO4]
    KABALOV, YK
    SIMONOV, MA
    IVANOV, VI
    MELNIKOV, OK
    BELOV, NV
    DOKLADY AKADEMII NAUK SSSR, 1973, 208 (06): : 1346 - 1348
  • [29] Hydrothermal Synthesis and Crystal Structure of Lithium Scandium Orthophosphate Li2Sc[H(PO4)2]. The Li2MIII[H(PO4)2] Family (MIII = Fe, Sc, In)
    Filaretov, A. A.
    Rusakov, D. A.
    Simonov, S. V.
    Khasanov, S. S.
    Komissarova, L. N.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2009, 54 (11) : 1750 - 1762
  • [30] Nonstoichiometry in the LiMo2O3(PO4)(2) structure: The molybdenotungsten monophosphate Li0.5MoWO3(PO4)(2)
    Leclaire, A
    Borel, MM
    Chardon, J
    Raveau, B
    MATERIALS RESEARCH BULLETIN, 1996, 31 (10) : 1257 - 1262
12345