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Palladium-catalysed hydroxylation and alkoxylation
被引:378
|作者:
Enthaler, Stephan
[1
]
Company, Anna
[1
,2
]
机构:
[1] Tech Univ Berlin, Dept Chem, D-10623 Berlin, Germany
[2] Univ Girona, Dept Quim, E-17071 Girona, Catalonia, Spain
关键词:
C-O BOND;
ARYL HALIDES;
REDUCTIVE ELIMINATION;
MOLECULAR-OXYGEN;
ALPHA-HYDROXYLATION;
DIRECT OXIDATION;
ASYMMETRIC DIHYDROXYLATION;
COUPLING REACTIONS;
BETA-KETOESTERS;
BUTYL ETHERS;
D O I:
10.1039/c1cs15085e
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
The formation of oxygen-carbon bonds is one of the fundamental transformations in organic synthesis. In this regard the application of palladium-based catalysts has been extensively studied during recent years. Nowadays it is an established methodology and the success has been proven in manifold synthetic procedures. This tutorial review summarizes the advances on palladium-catalysed C-O bond formation, means hydroxylation and alkoxylation reactions.
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页码:4912 / 4924
页数:13
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