Investigation of the Structure of Cs3(HSO4)2(H2PO4) Single Crystals

被引:5
|
作者
Makarova, I. P. [1 ]
Grebenev, V. V. [1 ]
Vasiliev, I. I. [1 ]
Dmitricheva, E. V. [1 ]
Komornikov, V. A. [1 ]
Dolbinina, V. V. [1 ]
机构
[1] Russian Acad Sci, Shubnikov Inst Crystallog, Moscow 119333, Russia
基金
俄罗斯基础研究基金会;
关键词
PHASE-TRANSITIONS; SUPERPROTONIC CONDUCTIVITY; (NH4)2SBF5;
D O I
10.1134/S1063774515040148
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Cs-3(HSO4)(2)(H2PO4) single crystals, obtained for the first time based on a systematic study of the phase diagram of the CsH2PO4-CsHSO4-H2O ternary system, have been studied by X-ray diffraction. The atomic structure of the crystals at room temperature is determined, and their structural features are analyzed.
引用
收藏
页码:498 / 507
页数:10
相关论文
共 50 条
  • [41] Synthesis and Structure of Ba(HSO4)2(H2SO4)3 and Sr(HSO4)2(H2SO4)
    Werner, C.
    Kemnitz, E.
    Worzala, H.
    Trojanov, S.
    Zeitschrift fuer Naturforschung. B, Journal of Chemical Sciences, 51 (07):
  • [42] Synthesis and structure of Zn(HSO4)2(H2SO4)2 and Cd(HSO4)2
    Kemnitz, E.
    Werner, C.
    Stiewe, A.
    Worzala, H.
    Trojanov, S.
    Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1996, 51 (01): : 14 - 18
  • [43] Structure and thermal behavior of the new superprotonic conductor Cs2(HSO4)(H2PO4).: (vol, B55, pg 937, 1999)
    Chisholm, CRI
    Haile, SM
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2000, 56 : 332 - 332
  • [44] Synthesis and structure of Zn(HSO4)2(H2SO4)(2) and Cd(HSO4)(2)
    Kemnitz, E
    Werner, C
    Stiewe, A
    Worzala, H
    Trojanov, S
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (01): : 14 - 18
  • [45] Dielectric, DSC and Raman studies of the phase transitions in NH4(HSO4)0.45(H2PO4)0.55 mixed crystals
    Bouattour, S
    Mhiri, T
    Kolsi, AW
    Romain, F
    PHASE TRANSITIONS, 1999, 70 (01) : 19 - 28
  • [46] New representatives of solid acid conductors: CsmHn((HSO4),(H2PO4))m+n
    Makarova, I.
    Grebenev, V.
    Dmitricheva, E.
    Komornikov, V.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2014, 70 : C65 - C65
  • [47] Impact of alkali ion chemistry on the properties of the M2(HSO4)(H2PO4) family of compounds (M = Cs, Rb, NH4, K).
    Chisholm, CRI
    Haile, SM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U696 - U696
  • [48] Spin diffusion and 1H spin-lattice relaxation in Cs2(HSO4)(H2PO4) containing a small amount of ammonium ions
    Hayashi, Shigenobu
    Jimura, Keiko
    SOLID STATE NUCLEAR MAGNETIC RESONANCE, 2017, 88 : 15 - 21
  • [49] SYNTHESIS AND STRUCTURE OF NEW SODIUM-HYDROGEN SULFATES NA(H3O)(HSO4)(2), NA-2(HSO4)(2)(H2SO4), AND NA(HSO4)(H2SO4)(2)
    TROJANOV, S
    WERNER, C
    KEMNITZ, E
    WORZALA, H
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (09): : 1617 - 1624
  • [50] X-ray diffraction study of Cs5(HSO4)3(H2PO4)2, a new solid acid with a unique hydrogen-bond network
    Haile, SM
    Calkins, PM
    JOURNAL OF SOLID STATE CHEMISTRY, 1998, 140 (02) : 251 - 265