Asymmetric synthesis of N-(diphenylphosphinyl)furfurylamine by the enantioselective alkylation of furfurylimine

被引：0
|
作者：
Zhang, HL
Zhang, XM
Li, X
Mi, AQ [1 ]
Cui, X
Jiang, YZ
机构：
[1] Chinese Acad Sci, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China
[2] Chinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2005年 / 16卷 / 09期
关键词：
asymmetric; dialkylzinc; N-(diphenylphosphinyl)furfurylamine;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Optically active N-(diphenylphosphinyl)furfurylamines 2 with good ee values were obtained by the enantioselective addition of dialkylzincs to furfuryl. imine 1 in the presence of chiral aminoalcohol derivatives and oxazolines.
引用
收藏
页码：1147 / 1150
页数：4
相关论文
共 50 条
  • [31] Chiral ligands for asymmetric synthesis:: enantioselective addition of diethylzinc to aromatic aldehydes catalyzed by chiral N-α-pyridylmethyl amino alcohols
    Yun, HY
    Wu, YJ
    Wu, YS
    Ding, KL
    Zhou, Y
    TETRAHEDRON LETTERS, 2000, 41 (52) : 10263 - 10266
  • [32] THE SYNTHESIS AND REACTIVITY OF N-DIPHENYLPHOSPHINYL AZIRIDINES
    OSBORN, HMI
    SWEENEY, JB
    HOWSON, B
    SYNLETT, 1994, (02) : 145 - 147
  • [33] Highly Enantioselective Organocatalytic Addition of Aldehydes to N-(Phenylmethylene)benzamides: Asymmetric Synthesis of the Paclitaxel Side Chain and Its Analogues
    Dziedzic, Pawel
    Schyman, Patric
    Kullberg, Martin
    Cordova, Armando
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (16) : 4044 - 4048
  • [34] Enantioselective Friedel-Crafts Alkylation of Indoles with Alkylidene Malonates Catalyzed by N,N′-Dioxide-Scandium(III) Complexes: Asymmetric Synthesis of β-Carbolines
    Liu, Yanling
    Shang, Deju
    Zhou, Xin
    Liu, Xiaohua
    Feng, Xiaoming
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (09) : 2055 - 2058
  • [35] Asymmetric synthesis of optically active fluorine-containing alcohols by the catalytic enantioselective alkylation of aldehydes
    Journal of Fluorine Chemistry, 84 (01):
  • [36] Asymmetric synthesis of (diene)Fe(CO)(3) complexes via catalytic enantioselective alkylation with dialkylzinc
    Takemoto, Y
    Baba, Y
    Noguchi, I
    Iwata, C
    TETRAHEDRON LETTERS, 1996, 37 (19) : 3345 - 3346
  • [37] Asymmetric synthesis of (diene)Fe(CO)3 complexes by a catalytic enantioselective alkylation using dialkylzincs
    Takemoto, Y
    Baba, Y
    Honda, A
    Nakao, S
    Noguchi, I
    Iwata, C
    Tanaka, T
    Ibuka, T
    TETRAHEDRON, 1998, 54 (51) : 15567 - 15580
  • [38] Asymmetric synthesis of optically active fluorine-containing alcohols by the catalytic enantioselective alkylation of aldehydes
    Hayase, T
    Sugiyama, T
    Suzuki, M
    Shibata, T
    Soai, K
    JOURNAL OF FLUORINE CHEMISTRY, 1997, 84 (01) : 1 - 5
  • [39] Design and synthesis of a s-triazene based asymmetric organocatalyst and its application in enantioselective alkylation
    Mangawa, Shrawan K.
    Singh, Ashawani K.
    Awasthi, Satish K.
    RSC ADVANCES, 2015, 5 (75) : 61144 - 61147
  • [40] ENANTIOSELECTIVE ALKYLATION OF CARBONYL-COMPOUNDS - THE ASYMMETRIC-SYNTHESIS OF ALPHA-SUBSTITUTED CYCLOALKANONES
    MEYERS, AI
    ERICKSON, GW
    WHITE, SK
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1980, 180 (AUG): : 64 - ORGN
12345