Synthesis and catalytic activity of binuclear titanium imido complexes

被引：16

作者：

Said, M ^{[1
]}

Hughes, DL ^{[1
]}

Bochmann, M ^{[1
]}

机构：

[1] Univ E Anglia, Sch Chem Sci, Wolfson Mat & Catalysis Ctr, Norwich NR4 7TJ, Norfolk, England

来源：

DALTON TRANSACTIONS | 2004年 / 03期

关键词：

D O I：

10.1039/b315711c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the N-P ligand (ArN)-N-P(SiMe3)(2) with TiCl4 affords the imido-bridged binuclear titanium complex [TiCl2(THF)(mu-NArP)](2) (Ar-P = m-C6H4PR2) which reacts with Ni(0) or Pd(II) to give heterotrinuclear compounds, while activation with methylaluminoxane generates a new type of imido-based ethene polymerisation catalyst that is tolerant of - PR2 functional groups.

引用

页码：359 / 360

页数：2

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