C-2-symmetric chiral zinc alkoxides as catalysts for the enantioselective addition of diethylzinc to aryl aldehydes

被引:59
|
作者
Prasad, KRK [1 ]
Joshi, NN [1 ]
机构
[1] NATL CHEM LAB,DIV ORGAN SYNTH,PUNE 411008,MAHARASHTRA,INDIA
关键词
D O I
10.1016/0957-4166(96)00235-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Various dialkoxides of zinc, magnesium and boron were examined for the enantioselective addition of diethylzinc to aryl aldehydes, Only zinc based reagent catalysed the reaction effectively providing up to 89% ee of the product. Copyright (C) 1996 Elsevier Science Ltd
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页码:1957 / 1960
页数:4
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