Decorating soft electrified interfaces: From molecular assemblies to nano-objects

被引：34

作者：

Poltorak, Lukasz ^{[1
]}

Gamero-Quijano, Alonso ^{[2
]}

Herzog, Gregoire ^{[2
]}

Walcarius, Alain ^{[2
]}

机构：

[1] Delft Univ Technol, Dept Chem Engn, Van Maasweg 9, NL-2629 HZ Delft, Netherlands

[2] Univ Lorraine, LCPME, CNRS, UMR 7564, 405 Rue Vandoeuvre, F-54600 Villers Les Nancy, France

来源：

APPLIED MATERIALS TODAY | 2017年 / 9卷

关键词：

Functionalized ITIES; Liquid-liquid interface; Nanomaterials; Membranes; Electrochemistry; LIQUID-LIQUID INTERFACE; IMMISCIBLE ELECTROLYTE-SOLUTIONS; OIL-WATER INTERFACE; POTENTIAL-DEPENDENT ADSORPTION; ION-PAIRING INTERACTIONS; SILICA THIN-FILMS; BAR 1,2-DICHLOROETHANE INTERFACE; BRUST-SCHIFFRIN SYNTHESIS; SOL-GEL PROCESS; LIQUID/LIQUID INTERFACE;

D O I：

10.1016/j.apmt.2017.10.001

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The interface formed between two immiscible electrolyte solutions (ITIES) constitutes a fantastic playground for the investigation of charge (under the form of either ion or electron) transfer processes. We have reviewed here the routes for the modification of such soft interfaces by an accurate electrochemicalcontrol. The three main strategies developed in the past four decades include (i) the electrochemically controlled assembly of molecules and nano-objects; (ii) the in situ electrogeneration of nanomaterialsand (iii) the use of ex situ synthesized membranes. Applications of functionalized ITIES in the fields of redox catalysis and electroanalysis of modified soft interfaces are also discussed. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：533 / 550

页数：18

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