Enabling High-Temperature and High-Voltage Lithium-Ion Battery Performance through a Novel Cathode Surface-Targeted Additive

被引:5
|
作者
Johnson, Noah M. [1 ]
Yang, Zhenzhen [1 ]
Bloom, Ira [1 ]
Zhang, Zhengcheng [1 ]
机构
[1] Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA
关键词
high temperature; high voltage; LCO; lithium-ion; electrolyte additive; hydroxamates; VINYLENE CARBONATE VC; TRANSITION-METAL DISSOLUTION; ELEVATED-TEMPERATURE; ELECTROLYTE ADDITIVES; IMPEDANCE SPECTROSCOPY; CYCLING PERFORMANCE; CAPACITY RETENTION; THERMAL-STABILITY; HIGH-PRECISION; BEHAVIOR;
D O I
10.1021/acsami.1c18493
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Lithium-ion batteries (LIBs) are being used in locations and applications never imagined when they were first conceived. To enable this broad range of applications, it has become necessary for LIBs to be stable to an ever broader range of conditions, including temperature and energy. Unfortunately, while negative electrodes have received a great deal of focus in electrolyte development, stabilization of positive electrodes remains an elusive target. Here, we report a novel additive that shows the ability to protect positive electrodes against elevated temperatures and voltages. This additive can be used in small quantities, and its targeted behavior allows it to remain functional in complex electrolyte packages. This can prove an effective approach to targeting specific aspects of cell performance.
引用
收藏
页码:59538 / 59545
页数:8
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