Synthesis of Zeolite-Zeolite (MFI-FAU) Composite Catalysts for the Isomerization of n-Hexane

被引:0
|
作者
Ghouri, Awais Sattar [1 ]
Usman, Muhammad Rashid [2 ]
机构
[1] Balochistan Univ Informat Technol Engn & Manageme, Dept Chem Engn, Fac Engn & Architecture, Balochistan 87100, Pakistan
[2] Univ Punjab, Inst Chem Engn & Technol, Lahore 54590, Pakistan
来源
JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN | 2017年 / 39卷 / 06期
关键词
Isomerization; Composite Catalysts; n-hexane; Y-Zeolite; ZSM-5; Y-ZEOLITE; ZSM-5; ZEOLITE; CONTROLLED DESILICATION; CONTROLLABLE SYNTHESIS; CRYSTALS; CRACKING; PERFORMANCE; PARTICLES; METHANOL; ACIDITY;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this research work, the aim is to produce a relatively novel zeolite-zeolite (MFI-FAU) composite catalyst having better potential of catalyzing isomerization of lighter hydrocarbons such as light naphtha, n-pentane, n-hexane, n-heptane and mixture thereof. A series of zeolite-zeolite (MFI-FAU) composite catalysts have been synthesized by incorporating previous practices and techniques. The catalytic performance of as-synthesized zeolite-zeolite (MFI-FAU) composite catalysts have been investigated by isomerizing 95% pure n-hexane in conventional fixed bed flow micro-reactor at temperature 200-240 degrees C under atmospheric pressure. In order to explore chemical and physical features of zeolite-zeolite (MFI-FAU) composite catalysts, they are examined and characterized using powder X-ray diffraction (XRD), scanning electron microscopy (SEM) coupled with energy-dispersive X-ray spectrometry (EDX), N-2 adsorption-desorption measurements (BET, BJH, t-plot measurements) and Fourier transform infrared (FTIR) spectroscopy equipped with attenuated total reflectance (ATR) arrangements.
引用
收藏
页码:919 / 933
页数:15
相关论文
共 50 条
  • [31] Sorption rate and thermal barriers in a gas-zeolite system:: Investigation of n-hexane sorption in MFI-type zeolite
    Wloch, J
    Kornatowski, J
    LANGMUIR, 2004, 20 (04) : 1180 - 1183
  • [32] Study of the mechanism of the cracking of n-hexane over zeolite I. Cracking chain length of n-hexane over zeolite
    Yan, Lijun
    Fu, Jun
    He, Mingyuan
    Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section), 2000, 16 (03): : 15 - 26
  • [33] Aromatization of n-hexane over zeolite catalysts of varying silica alumina ratio
    Ayad, Z.S.
    Journal of Engineering and Applied Science, 2002, 49 (02): : 387 - 403
  • [34] REACTIONS OF N-HEXANE OVER PT-ZEOLITE CATALYSTS OF DIFFERENT ACIDITY
    ZHAN, Z
    MANNINGER, I
    PAAL, Z
    BARTHOMEUF, D
    JOURNAL OF CATALYSIS, 1994, 147 (01) : 333 - 341
  • [35] ISOMERIZATION OF N-HEXANE ON PLATINUM DEALUMINATED MORDENITE CATALYSTS .1. INFLUENCE OF THE SILICON-TO-ALUMINUM RATIO OF THE ZEOLITE
    GUISNET, M
    FOUCHE, V
    BELLOUM, M
    BOURNOVILLE, JP
    TRAVERS, C
    APPLIED CATALYSIS, 1991, 71 (02): : 283 - 293
  • [36] Characterization of acidity and porosity of zeolite catalysts by the equilibrated thermodesorption of n-hexane and n-nonane
    Makowski, Waclaw
    Gil, Barbara
    Majda, Dorota
    CATALYSIS LETTERS, 2008, 120 (1-2) : 154 - 160
  • [37] Characterization of Acidity and Porosity of Zeolite Catalysts by the Equilibrated Thermodesorption of n-Hexane and n-Nonane
    Wacław Makowski
    Barbara Gil
    Dorota Majda
    Catalysis Letters, 2008, 120 : 154 - 160
  • [38] Design of efficient zeolite sensor materials for n-hexane
    Yang, Ping
    Ye, Xingnan
    Lau, Choiwan
    Li, Zengxi
    Liu, Xia
    Lu, Jianzhong
    ANALYTICAL CHEMISTRY, 2007, 79 (04) : 1425 - 1432
  • [39] Combined in situ XAS and DFT studies on the role of Pt in zeolite-supported metal catalysts for selective n-hexane isomerization
    Injongkol, Yuwanda
    Khemthong, Pongtanawat
    Yodsin, Nuttapon
    Wongnongwa, Yutthana
    Sosa, Narongrit
    Youngjan, Saran
    Butburee, Teera
    Rungtaweevoranit, Bunyarat
    Kiatphuengporn, Sirapassorn
    Wittayakun, Jatuporn
    Roessner, Frank
    Jungsuttiwong, Siriporn
    FUEL, 2022, 314
  • [40] Temperature programmed desorption of n-hexane and n-heptane from MFI and FAU zeolites
    Makowski, Waclaw
    Majda, Dorota
    JOURNAL OF POROUS MATERIALS, 2007, 14 (01) : 27 - 35