Polymerisation of cyclic monomers, 8 -: Synthesis and radical polymerisation of hybrid 2-vinylcyclopropanes

被引：0
|
作者：
Moszner, N [1 ]
Völkel, T [1 ]
Fischer, UK [1 ]
Rheinberger, V [1 ]
机构：
[1] Ivoclar AG, FL-9494 Schaan, Liechtenstein
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 1999年 / 20卷 / 01期
关键词：
D O I：
10.1002/(SICI)1521-3927(19990101)20:1<33::AID-MARC33>3.0.CO;2-I
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Hybrid 2-vinylcyclopropanes were synthesised by the esterification of 1-methoxycarbonyl-2- vinylcyclopropane-1-carboxylic acid with hydroxy group containing (meth)acrylates in the presence of 1,3- dicyclohexylcarbodiimide (DCC). The structure of the new hybrid monomers was confirmed by elemental analysis, IR, H-1 NMR and C-13 NMR spectroscopy. The radical polymerisation of the hybrid monomers in bulk with 2,2'-azoisobutyronitrile (AIBN) results in transparent cross-linked polymers, whereas solution polymerisation partially results in soluble polymers with pendant 2-vinylcyclopropyl groups.
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页码：33 / 35
页数：3
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