Polymerisation of cyclic monomers, 8 -: Synthesis and radical polymerisation of hybrid 2-vinylcyclopropanes

被引：0

作者：

Moszner, N ^{[1
]}

Völkel, T ^{[1
]}

Fischer, UK ^{[1
]}

Rheinberger, V ^{[1
]}

机构：

[1] Ivoclar AG, FL-9494 Schaan, Liechtenstein

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1999年 / 20卷 / 01期

关键词：

D O I：

10.1002/(SICI)1521-3927(19990101)20:1<33::AID-MARC33>3.0.CO;2-I

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Hybrid 2-vinylcyclopropanes were synthesised by the esterification of 1-methoxycarbonyl-2- vinylcyclopropane-1-carboxylic acid with hydroxy group containing (meth)acrylates in the presence of 1,3- dicyclohexylcarbodiimide (DCC). The structure of the new hybrid monomers was confirmed by elemental analysis, IR, H-1 NMR and C-13 NMR spectroscopy. The radical polymerisation of the hybrid monomers in bulk with 2,2'-azoisobutyronitrile (AIBN) results in transparent cross-linked polymers, whereas solution polymerisation partially results in soluble polymers with pendant 2-vinylcyclopropyl groups.

引用

页码：33 / 35

页数：3

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