New bismuth ion conducting solid electrolyte

被引：7
|
作者：
Katayama, Hirokazu [1 ]
Tamura, Shinji [1 ]
Imanaka, Nobuhito [1 ]
机构：
[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suite, Osaka 5650871, Japan
来源：
SOLID STATE IONICS | 2011年 / 192卷 / 01期
关键词：
Trivalent cation; Bismuth ion; NASICON-type; NASICON-TYPE PHOSPHATE; SYSTEM; TRANSPORT;
D O I：
10.1016/j.ssi.2010.05.059
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new trivalent bismuth ion conducting solid electrolyte, (Bi(x)Ge(1-x))(4/(4-x))Ta(PO(4))(3), was successfully developed by selecting the NASICON-type GeTa(PO(4))(3) as the mother solid. Although bismuth has two kinds of valence states of +3 and +5, it was clear that pure trivalent Bi(3+) ion conduction, without any electronic conduction by a valence change of bismuth in the oxygen pressure range over 10(-3) Pa, was realized by selecting the crystal structure and constituents of the solid. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：134 / 136
页数：3
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