New bismuth ion conducting solid electrolyte

被引：7

作者：

Katayama, Hirokazu ^{[1
]}

Tamura, Shinji ^{[1
]}

Imanaka, Nobuhito ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suite, Osaka 5650871, Japan

来源：

SOLID STATE IONICS | 2011年 / 192卷 / 01期

关键词：

Trivalent cation; Bismuth ion; NASICON-type; NASICON-TYPE PHOSPHATE; SYSTEM; TRANSPORT;

D O I：

10.1016/j.ssi.2010.05.059

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new trivalent bismuth ion conducting solid electrolyte, (Bi(x)Ge(1-x))(4/(4-x))Ta(PO(4))(3), was successfully developed by selecting the NASICON-type GeTa(PO(4))(3) as the mother solid. Although bismuth has two kinds of valence states of +3 and +5, it was clear that pure trivalent Bi(3+) ion conduction, without any electronic conduction by a valence change of bismuth in the oxygen pressure range over 10(-3) Pa, was realized by selecting the crystal structure and constituents of the solid. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：134 / 136

页数：3

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