The 4.4 MeV photon reference field described in ISO 4037 is produced by the C-12(P,P',)C-12 (E-x = 4.4389 MeV) reaction using a thick elemental carbon target and a proton beam with an energy of 5.7 MeV. The relative abundance of the isotope C-13 in elemental carbon is 1.10%. Therefore, the 4.4 MeV photon field is contaminated by neutrons produced by the C-13( p,n) N-13 reaction (Q = -3.003 MeV). The ambient dose equivalent H*(10) produced by these neutrons is of the same order of magnitude as the ambient dose equivalent produced by the 4.4 MeV photons. For the calibration of dosemeters, especially those also sensitive to neutrons, the spectral fluence distribution of these neutrons has to be known in detail. On the other hand, a mixed photon/neutron field is very useful for the calibration of tissue-equivalent proportional counters (TEPC), if this field combines a high-linear energy transfer (LET) component produced by low-energy neutrons and a low-LET component resulting from photons with about the same ambient dose equivalent and energies up to 7 MeV. Such a mixed field was produced at the PTB accelerator facility using a thin CaF2 + C-nat target and a 5.7 MeV proton beam.