Electrophysical properties of layered perovskites LnBaCo2-x Cu x O5+δ (Ln = Sm, Nd) for solid oxide fuel cells

被引：10
|
作者：
Zhuravleva, T. A. [1 ]
机构：
[1] Russian Acad Sci, Inst High Temp Electrochem, Ural Branch, Ekaterinburg, Russia
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2011年 / 47卷 / 06期
关键词：
electric conductivity; linear thermal expansion coefficient (LTEC); LnBaMe(2)O(5+delta); OXYGEN NONSTOICHIOMETRY; ELECTRICAL-PROPERTIES; CATHODES; ION;
D O I：
10.1134/S1023193511060164
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The influence of doping with copper oxide on the phase composition, electric conductivity, and linear thermal expansion coefficient (LTEC) of SmBaCo2O5 + delta and NdBaCo2O5 + delta was studied. The sample homogeneity region has been determined with using XRD. The samples conductivity decreased as the dopant concentration increased. The character of the temperature dependence of conductivity changed at high copper contents. In a reductive atmosphere, the conductivity of the samples at first decreased and then remained constant. The linear thermal expansion coefficient decreased as the amount of the incorporated dopant increased.
引用
收藏
页码：676 / 680
页数：5
相关论文
共 50 条
  • [41] Combinative energy, oxygen deficiency and superconductivity in LnBa2Cu3O7-x (Ln=Nd, Er, Sm)
    Wang, SX
    Liu, WL
    Han, SH
    Zhang, H
    CHINESE PHYSICS, 2003, 12 (11): : 1291 - 1295
  • [42] Thermal Expansion Properties of Sr1-xLaxTiO3-δ (0 ≤ x ≤ 0.3) Perovskites in Solid Oxide Fuel Cells
    Wang, Z.
    Mori, M.
    Itoh, T.
    SOLID OXIDE FUEL CELLS 11 (SOFC-XI), 2009, 25 (02): : 2617 - 2624
  • [43] Double substituted NdBa(Fe,Co,Cu)2O5+δ layered perovskites as cathode materials for intermediate-temperature solid oxide fuel cells-correlation between structure and electrochemical properties
    Klyndyuk, Andrei, I
    Kharytonau, Dzmitry S.
    Mosialek, Michal
    Chizhova, Ekaterina A.
    Komenda, Anna
    Socha, Robert P.
    Zimowska, Malgorzata
    ELECTROCHIMICA ACTA, 2022, 411
  • [44] Electrochemical performance of Pr1-xYxBaCo2O5+δ layered perovskites as cathode materials for intermediate-temperature solid oxide fuel cells
    Zhao, Hailei
    Zheng, Yu
    Yang, Chunyang
    Shen, Yongna
    Du, Zhihong
    Swierczek, Konrad
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (36) : 16365 - 16372
  • [45] RUTHENIUM-BASED LAYERED CUPRATES RUSR(2)LNCU(2)O(8) AND RUSR2(LN(1+X) CE-1-X) CU2O10 (LN=SM, EU AND GD)
    BAUERNFEIND, L
    WIDDER, W
    BRAUN, HF
    PHYSICA C, 1995, 254 (1-2): : 151 - 158
  • [46] Electrochemical performance of solid oxide fuel cells with Sm, Nd co-doped Ce0.85(SMxNd1-x)0.15O2-δ electrolyte
    Ma, Lei
    Zhao, Kai
    Kim, Bok-Hee
    Li, Qian
    Huang, Jinliang
    CERAMICS INTERNATIONAL, 2015, 41 (05) : 6391 - 6397
  • [47] NdBaMn2O5+δ layered perovskite as an active cathode material for solid oxide fuel cells
    Abdalla, Abdalla M.
    Hossain, Shahzad
    Zhou, Jun
    Petra, Pg M. I.
    Erikson, Stene
    Savaniu, Cristian D.
    Irvine, John T. S.
    Azad, Abul K.
    CERAMICS INTERNATIONAL, 2017, 43 (17) : 15932 - 15938
  • [48] Synthesis and properties of LST-x%Bi2O3 anode materials for solid oxide fuel cells
    Xin Hui Zhang
    Jie Zhang
    Chao Yuan
    Er Jun Liang
    RENEWABLE AND SUSTAINABLE ENERGY, PTS 1-7, 2012, 347-353 : 3325 - +
  • [49] Phase stability, thermal, electrical and structural properties of (Bi2O3)1-x-y(Sm2O3)x(CeO2)y electrolytes for solid oxide fuel cells
    Polat, Yasin
    Ari, Mehmet
    Dagdemir, Yilmaz
    PHASE TRANSITIONS, 2017, 90 (04) : 387 - 398
  • [50] ReBaCo2-xMnxO5+δ (Re: rare earth element) layered perovskites for application as cathodes in Solid Oxide Fuel Cells
    Olszewska, Anna
    Swierczek, Konrad
    ENERGY AND FUELS 2018, 2019, 108
12345