Carbamoyl radicals from Se-phenylselenocarbamates: Intramolecular additions to alkenes

被引：22
|
作者：
Rigby, JH [1 ]
Danca, DM [1 ]
Horner, JH [1 ]
机构：
[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA
来源：
TETRAHEDRON LETTERS | 1998年 / 39卷 / 46期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/S0040-4039(98)01830-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of 5 exo-trig cyclizations of carbamoyl radicals generated from readily available Se-phenylselenocarbamates is reported. Kinetic studies indicate that the rate constant of this cyclization exceeds 1x10(8)s(-1) in several cases. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：8413 / 8416
页数：4
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