Electrochemical influence of tridentate polypyrazolylborate ligands:: Syntheses and electrochemistry of bis(η3-polypyrazolylborato)ruthenium(II) complexes

被引：14
|
作者：
Onishi, M
Kumagae, S
Asai, K
Kawano, H
Shigemitsu, Y
机构：
[1] Nagasaki Univ, Dept Appl Chem, Fac Engn, Nagasaki 8528521, Japan
[2] Nagasaki Univ, Grad Sch Sci & Technol, Nagasaki 8528521, Japan
[3] Ind Technol Ctr Nagasaki, Nagasaki 8560026, Japan
来源：
CHEMISTRY LETTERS | 2001年 / 02期
关键词：
D O I：
10.1246/cl.2001.96
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Concerning electrochemically reversible [Ru(III)]/[Ru(II)] redox couples of the substituted bis(eta (3)-polypyrazolylborato)-ruthenium(II) complexes [Ru(L-1)(L-2)], two polypyrazolylborate ligands, L-1 and L-2, were independently exerted on the oxidation half-wave potentials (E-1/2) of the couples. Relative contributions DeltaE(L) of the respective polypyrazolylborates to the E-1/2 values were evaluated.
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页码：96 / 97
页数：2
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