Bis[2-(2-aminoethyl)-1H-benzimidazole-k2 N2, N3] zinc(II) bis(perchlorate)

被引:1
|
作者
Zhang, Jine [1 ]
Li, Yanping [1 ]
Huo, Fangjun [1 ]
Zhang, Zhigang [1 ]
机构
[1] Shanxi Univ, Educ Minist, Inst Mol Sci, Chem Biol & Mol Engn Lab, Taiyuan 030006, Shanxi, Peoples R China
关键词
D O I
10.1107/S160053680706610X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Zn( C9H11N3)(2)](ClO4)(2), the Zn-II atom resides on a crystallographic twofold axis and is coordinated by two benzimidazole N[Zn center dot center dot center dot N = 1.993 (4) angstrom] and two amine N atoms [Zn center dot center dot center dot N = 2.036 (4) angstrom] in a distorted tetrahedral geometry. The crystal packing is dominated by N-H center dot center dot center dot O interactions involving the perchlorate anions and pi-pi stacking interactions with an interplanar separation of 3.42 angstrom. A weak C-H center dot center dot center dot O interaction is also present.
引用
收藏
页码:M182 / U1735
页数:10
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