Liquid-liquid equilibria of quaternary and quinary systems including sulfolane at 298.15 K

被引:23
|
作者
Chen, J [1 ]
Mi, JG [1 ]
Fei, WY [1 ]
Li, ZC [1 ]
机构
[1] Tsing Hua Univ, Dept Chem Engn, Beijing 100084, Peoples R China
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D O I
10.1021/je0001983
中图分类号
O414.1 [热力学];
学科分类号
摘要
Liquid-liquid equilibria (LLE) were measured at 298.15 K for three quaternary systems-hexane + heptane + toluene + sulfolane, heptane + octane + m-xylene + sulfolane and heptane + benzene + toluene + sulfolane-and for two quinary systems-hexane + heptane + toluene + m-xylene + sulfolane. and heptane + octane + benzene + m-xylene + sulfolane. The equilibrium data of these systems are compared with those predicted using the nonrandom two-liquid (NRTL) model with parameters fitted from ternary LLE data. The predicted data are in good agreement with experimental ones.
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页码:169 / 171
页数:3
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