Structure and viscoelastic properties of segmented polyurethane blends

被引:0
|
作者
Takigawa, T
Oodate, M
Urayama, K
Masuda, T
机构
[1] KYOTO UNIV,INST CHEM RES,UJI,KYOTO 611,JAPAN
[2] KYOTO UNIV,DIV MAT CHEM,SAKYO KU,KYOTO 60601,JAPAN
关键词
D O I
10.1002/(SICI)1097-4628(19960307)59:10<1563::AID-APP9>3.0.CO;2-K
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Structure and viscoelastic properties of segmented polyurethanurea (SPU) blends were investigated. The glass transition temperature (T-g) of poly(tetramethylene glycohol) (PTMG) in a soft-segment block of the component SPU increased with decreasing molecular weight of PTMG. The blend samples showed two T(g)s of PTMG in the temperature dispersions of the loss modulus (E '') and loss tangent (tan delta). The value of E' in the leathery region for the blend specimens was strongly affected by the morphology. The blends were considered to have a morphology where PTMG differing in molecular weight was localized. (C) 1996 John Wiley & Sons, Inc.
引用
收藏
页码:1563 / 1568
页数:6
相关论文
共 50 条
  • [31] Development of nanoscale morphology and role of viscoelastic phase separation on the properties of epoxy/recycled polyurethane blends
    Reghunadhan, Arunima
    Datta, Janusz
    Kalarikkal, Nandakumar
    Thomas, Sabu
    POLYMER, 2017, 117 : 96 - 106
  • [32] Nanophase separation in segmented polyurethane elastomers:: Effect of specific interactions on structure and properties
    Pukanszky, Bela
    Bagdi, Kristof
    Tovolgyi, Zsuzsa
    Varga, Jozsef
    Botz, Lajos
    Hudak, Stephan
    Doczi, Tamas
    Pukanszky, Bela
    EUROPEAN POLYMER JOURNAL, 2008, 44 (08) : 2431 - 2438
  • [33] Relationships between interfacial properties and structure of segmented polyurethane having functional groups
    Nakamae, K
    Nishino, T
    Asaoka, S
    Sudaryanto
    INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 1999, 19 (05) : 345 - 351
  • [34] Effects of thermal annealing of segmented-polyurethane on surface properties, structure and antithrombogenicity
    Atsuo Takahashi
    Rio Kita
    Makoto Kaibara
    Journal of Materials Science: Materials in Medicine, 2002, 13 : 259 - 264
  • [35] Effects of thermal annealing of segmented-polyurethane on surface properties, structure and antithrombogenicity
    Takahashi, A
    Kita, R
    Kaibara, M
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2002, 13 (03) : 259 - 264
  • [36] The structure and properties of viscoelastic polyurethane foams with fillers from coffee grounds
    Auguscik-Krolikowska, Monika
    Ryszkowska, Joanna
    Ambroziak, Agata
    Szczepkowski, Leonard
    Oliwa, Rafal
    Oleksy, Mariusz
    POLIMERY, 2020, 65 (10) : 708 - 718
  • [37] STRUCTURE AND VISCOELASTIC PROPERTIES OF POLYCYANURATE-POLYURETHANE SEMIINTERPENETRATING POLYMER NETWORKS
    BROVKO, AA
    FAINLEIB, AM
    SHANTALII, TA
    SERGEEVA, LM
    DAVIDENKO, VV
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1994, 36 (07): : 1132 - 1136
  • [38] FEATURES OF THE STRUCTURE AND PROPERTIES OF SEGMENTED OLIGODIENE POLYURETHANE RUBBERS HAVING RIGID SEGMENTS OF VARIOUS STRUCTURE
    KERCHA, YY
    OLEINIK, SP
    SHELKOVNIKOVA, LA
    DASHEVSKII, LI
    BOGDANOVICH, VA
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1990, 32 (05): : 1021 - 1026
  • [39] The Effects of Thermoplastic Polyurethane on the Structure and Mechanical Properties of Modified Polypropylene Blends
    Lin, Ting An
    Lou, Ching -Wen
    Lin, Jia-Horng
    APPLIED SCIENCES-BASEL, 2017, 7 (12):
  • [40] Thermal analysis of the structure of segmented polyurethane elastomers
    Bagdi, Kristof
    Molnar, Kinga
    Pukanszky, Bela, Jr.
    Pukanszky, Bela
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 98 (03) : 825 - 832