Mercuration with mercury(II) trifluoroacetate of (η6-aniline)- or (N,N-dimethylaniline)-(η5-cyclopentadienyl)iron(II)

被引：0
|
作者：
Boev, AM [1 ]
Moskalenko, AI [1 ]
Boev, VI [1 ]
机构：
[1] Lipetsk State Pedagog Univ, Lipetsk, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2003年 / 73卷 / 10期
关键词：
D O I：
10.1023/B:RUGC.0000016012.56251.ef
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of mercury(II) trifluoroacetate with the hexafluorophosphate of the eta(6)-aniline-eta(5)-cyclopentadienyliron(II) cation under reflux in dry ethanol gives rise to N-mono- and N,N-disubstituted mercury-containing salts of this cation. The same mercury-containing salts have been synthesized by the action of mercury(II) trifluoroacetate on the deprotonation product of the (eta(6)-aniline)(eta(5)-cyclopentadienyl)-iron(II) cation. Direct mercuration of the [eta(6)-(N,N-dimethylaniline)](eta(5)-cyclopentadienyl)iron(II) cation into the para position of the benzene ring of the arene ligand has been performed. The reactivity of the compounds obtained has been studied.
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页码：1511 / 1515
页数：5
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