Rutheniurn(II) meso-tetra-(benzo-15-crown-5)-porphyrinates:: Synthesis and spectroscopic investigation

被引：5

作者：

Enakieva, Yuliya Yu. ^{[1
]}

Gorbunova, Yuliya G. ^{[1
]}

Tsivadze, Asian Yu. ^{[1
]}

Stern, Christine ^{[2
]}

Guilard, Roger ^{[2
]}

机构：

[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 119991, Russia

[2] Univ Bourgogne, Inst Chim Mol, CNRS, UMR 5260,Fac Sci Mirande, F-21078 Dijon, France

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2007年 / 11卷 / 11-12期

关键词：

porphyrin; crown ether; ruthenium; N-donor ligand;

D O I：

10.1142/S1088424607001004

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of novel ruthenium(II) meso-tetra-(benzo-15-crown-5)-porphyrinates, meso-[(B15C5)(4)Por]Ru(CO)(MeOH) (1) and meso-[(B15C5)(4)Por]Ru(L)(2) (2)-(4) (meso-[(B15C5)(4)Por](2)= 5, 10, 15,20-tetrakis-(benzo-15-crown-5)-porphyrinato-dianion; L = pyridine (py), pyrazine (pyz), 4,4'-bipyridyl (4,4'-bpy)), where CO and MeOH, or two N-donor ligands are axially coordinated to the central metal, are reported. The metalation of the free ligand performed by the reaction of Ru-3(CO)(12) with meso-[(B15C5)(4)Por]H-2 in 1,2,4-trichlorobenzene (TCB, bp = 215 degrees C), gives (1) in a high yield. The synthesis of (2)-(4) involves the decarborylation of (1) with trimethylamine N-oxide ((CH,),NO) in the presence of an excess of the N-donor ligand. The coordination of the axially bonded ligands is evidenced by different spectroscopic data. Copyright (c) 2007 Society of Porphyrins & Phthalocyanines.

引用

页码：883 / 890

页数：8

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