Surface induced ordering of micelles at the solid-liquid interface

被引：30
|
作者：
Gerstenberg, MC
Pedersen, JS
Smith, GS
机构：
[1] Riso Natl Lab, Dept Condensed Matter Phys & Chem, DK-4000 Roskilde, Denmark
[2] Univ Calif Los Alamos Natl Lab, Manual Lujan Jr Neutron Scattering Ctr MSH805, Los Alamos, NM 87545 USA
来源：
PHYSICAL REVIEW E | 1998年 / 58卷 / 06期
关键词：
D O I：
10.1103/PhysRevE.58.8028
中图分类号：
O35 [流体力学]; O53 [等离子体物理学];
学科分类号：
070204 ; 080103 ; 080704 ;
摘要：
The surface induced ordering of triblock copolymer micelles in aqueous solution was measured with neutron reflectivity far above the critical micelle concentration. The scattering length density profiles showed a clear indication of ordered layers of micelles perpendicular to a quartz surface. The structure and interactions of the micelles were modeled in detail. The convolution of the center distribution of the micelles, obtained from Monte Carlo simulations of hard spheres at a hard wall, and the projected density of the micelle showed excellent agreement with the experimental profiles. [S1063-651X(98)06712-9].
引用
收藏
页码：8028 / 8031
页数：4
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