Hydrogen Storage in Magnesium Hydride: The Molecular Approach

被引：104
|
作者：
Harder, Sjoerd [1 ]
Spielmann, Jan [2 ]
Intemann, Julia [1 ]
Bandmann, Heinz [2 ]
机构：
[1] Univ Groningen, Stratingh Inst Chem, NL-9747 AG Groningen, Netherlands
[2] Univ Duisburg Essen, Fak Chem, D-45117 Duisburg, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 18期
关键词：
cluster compounds; hydrides; hydrogen storage; magnesium; CALCIUM; COMPLEXES; CATALYSTS; AMMONIA; ADDUCT; H-1;
D O I：
10.1002/anie.201101153
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Big can be small: The largest ligand-stabilized magnesium hydride cluster, containing 8 Mg2+ and 10 H- ions, is a model for the smallest sub-nanometer-sized hydrogen storage material. This molecular cluster displays magnetic hydride-hydride coupling (see picture) and complete hydrogen desorption at the record-low temperature of 200 °C. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：4156 / 4160
页数：5
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