Dinickel(II) complex of N, N′-propylenebis(3-formyl-5-tert-butylsalicylaldimine): X-ray structural characterization and bio-relevant catalytic activity

被引：16
|
作者：
Das, Sudhanshu [2 ]
Maiti, Pali [2 ]
Ghosh, Totan [2 ]
Zangrando, Ennio [1 ]
Das, Debasis [2 ]
机构：
[1] Univ Trieste, Dipartimento Sci Chim & Farmaceut, I-34127 Trieste, Italy
[2] Univ Calcutta, Dept Chem, Kolkata 700009, India
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 15卷
关键词：
Nickel complex; 'Side-off' compartmental ligand; Crystal structure; Catecholase activity; UV-vis spectroscopy; DINUCLEAR COPPER(II) COMPLEXES; CATECHOL OXIDASE ACTIVITY; METAL-COMPLEXES; SPECTROSCOPIC CHARACTERIZATION; COMPARTMENTAL LIGANDS; MACROCYCLIC LIGANDS; ADDUCTS;
D O I：
10.1016/j.inoche.2011.10.041
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel dinuclear nickel(II) complex, [Ni2L(NO3)(H2O)(3)]NO3 (where L is a 'side-off' compartmental ligand obtained by [1 + 2] condensation of 1,3-diaminopropane and 2,6-diformyl-4-tert-butylphenol) has been synthesized and characterized by routine physicochemical techniques as well as by X-ray single crystal structure analysis. Structure determination reveals that the two nickel ions, separated by 3.0824(9) angstrom, occupy the N2O2 and O-4 compartments of the Schiff base ligand. The immediate coordination environment of each nickel ion is octahedral and the species adopts an umbrella bowed conformation. The catalytic activity of the complex for the oxidation of 3,5-di-tert-butylcatechol to the corresponding o-quinone in methanol solvent has been studied by UV-vis spectroscopic technique. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：266 / 268
页数：3
相关论文
共 50 条
  • [21] Spectroscopic, EPR, X-ray structural, and DFT studies of the complex compound of N4-donor ligand with copper(II)
    Yilmaz, Ismail
    Acar, Nursel S.
    Coles, Simon J.
    Sengul, Abdurrahman
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1214
  • [22] Multinuclear Cu(II) Schiff Base Complex as Efficient Catalyst for the Chemical Coupling of CO2 and Epoxides: Synthesis, X-ray Structural Characterization and Catalytic Activity
    Ulusoy, Mahmut
    Sahin, Onur
    Kilic, Ahmet
    Buyukgungor, Orhan
    CATALYSIS LETTERS, 2011, 141 (05) : 717 - 725
  • [23] Multinuclear Cu(II) Schiff Base Complex as Efficient Catalyst for the Chemical Coupling of CO2 and Epoxides: Synthesis, X-ray Structural Characterization and Catalytic Activity
    Mahmut Ulusoy
    Onur Şahin
    Ahmet Kilic
    Orhan Büyükgüngör
    Catalysis Letters, 2011, 141 : 717 - 725
  • [24] Crystal structure and magnetic properties of the binuclear copper(II) complex based on 1,3-diaminopropan-2-ol N,N'-bis(3-formyl-5-tert-butylsalicylidene)
    Tupolova, Yu. P.
    Popov, L. D.
    Levchenkov, S. I.
    Shcherbakov, I. N.
    Suponitskii, K. Yu.
    Ionov, A. M.
    Kogan, V. A.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2011, 37 (07) : 552 - 555
  • [25] Crystal structure and magnetic properties of the binuclear copper(II) complex based on 1,3-diaminopropan-2-ol N,N′-bis(3-formyl-5-tert-butylsalicylidene)
    Yu. P. Tupolova
    L. D. Popov
    S. I. Levchenkov
    I. N. Shcherbakov
    K. Yu. Suponitskii
    A. M. Ionov
    V. A. Kogan
    Russian Journal of Coordination Chemistry, 2011, 37 : 552 - 555
  • [26] THE REACTION OF FE(II) WITH ETHYLTHIOXANTHATE - ISOLATION AND X-RAY STRUCTURAL CHARACTERIZATION OF [(CH3)4N][FE(S2CSC2H5)3]
    HENKEL, G
    STRASDEIT, H
    SIMON, W
    KREBS, B
    INORGANICA CHIMICA ACTA-LETTERS, 1983, 76 (04): : L207 - L208
  • [27] Synthesis, X-ray structural characterization, and catalytic property of an end-to-end azido-bridged polymeric manganese(III) complex derived from N,N′-bis(5-fluorosalicylidene)-1,2-diaminoethane
    Lei, Yan
    Yang, Qiwen
    INORGANIC AND NANO-METAL CHEMISTRY, 2017, 47 (03) : 446 - 449
  • [28] STRUCTURAL RESEARCHES ON COPPER(II) COMPLEXES WITH VITAMIN-B6 DERIVATIVES - X-RAY STRUCTURES OF BIS(N-TERT-BUTYL-PYRIDOXYLIDENEIMINATO)COPPER(II) AND BIS(N-TERT-BUTYL-PYRIDOXYLIDENEIMINATO)COPPER(II)-METHANOL (1-1/3)
    BIGOLI, F
    LANFRANCHI, M
    LEPORATI, E
    PELLINGHELLI, MA
    INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1983, 80 (03): : 135 - 143
  • [29] X-RAY STRUCTURAL CHARACTERIZATION OF [ET4N+]3[BIFE4(CO)163-]
    CHURCHILL, MR
    FETTINGER, JC
    WHITMIRE, KH
    LAGRONE, CB
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 303 (01) : 99 - 109
  • [30] Synthesis, X-Ray Structural Characterization, and Catalytic Property of Dioxomolybdenum(VI) Complexes With N′-(3-Bromo-2-hydroxybenzylidene)-2-hydroxybenzohydrazide and N′-(5-Chloro-2-hydroxybenzylidene)-4-nitrobenzohydrazide
    Lei, Yan
    Yang, Qiwen
    Chen, Gangcai
    Yang, Qingling
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2014, 44 (04) : 590 - 597
12345