Simple synthesis of rice husk hollow carbon-coated flower ZnO for the anode in a high performance lithium-ion battery

被引:20
|
作者
Li, Yi [1 ,2 ]
Huang, Yan [1 ,2 ]
Wang, Xiaofeng [3 ]
Liu, Weiping [4 ]
Yu, Kaifeng [1 ,2 ]
Liang, Ce [1 ,2 ]
机构
[1] Jilin Univ, Minist Educ, Key Lab Automobile Mat, Changchun 130025, Peoples R China
[2] Jilin Univ, Coll Mat Sci & Engn, Changchun 130025, Peoples R China
[3] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130022, Peoples R China
[4] Jilin Univ, Coll Instrumentat & Elect Engn, Changchun 130025, Peoples R China
关键词
Anode material; Biomass carbon; Flower zinc oxide; Composite; ENHANCED ELECTROCHEMICAL PERFORMANCE; FACILE SYNTHESIS; REVERSIBLE CAPACITY; NANOROD ARRAYS; NANOPARTICLES; FABRICATION; NANOSHEETS; SHELL; MICROSPHERES; FRAMEWORK;
D O I
10.1016/j.jpcs.2020.109540
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, a simple hydrothermal method was used to prepare flower-like zinc oxide, which was then combined with biomass hollow carbon derived from rice husk (rice hull cellulose, RHC) under hydrothermal conditions to obtain a ZnO/RHC composite material. The ZnO/RHC composite was used as the anode in lithium-ion batteries and it exhibited excellent electrochemical performance and cycling stability due to its special microstructure. In the ZnO/RHC composite, the sheet structure comprising zinc oxide was coated on the biomass carbon layer of the hollow spherical structure to form numerous conductive networks, thereby improving the electrochemical properties of the ZnO/RHC. The composite provided a reversible specific capacity of 1002.5 mA h g(-1) after 160 cycles at 0.2C, which is higher than the theoretical specific capacity of zinc oxide (978 mA h g(-1)). This material may facilitate the efficient and simple preparation of high performance lithium-ion battery anode materials.
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页数:8
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