In this article the influence of mechanical activation on sintering process of magnesium-titanate and barium-zinc-titanate ceramics has been investigated. Both non-activated and mixtures treated in planetary ball mill for 80 minutes were sintered at 1100 degrees C and 1300 degrees C. The influence of mechanical activation on phase composition and crystal structure has been analyzed by XRD, while the effect of activation and sintering process on microstructure was investigated by scanning electron microscopy. It has been established that temperature of 1100 degrees C was to low to induce final sintering stage for both systems. Moreover, we concluded that barium-zinc-titanate ceramics exhibited better sinterability than magnesium-titanate ceramics.