SYNTHESIS OF RUTHENIUM(II) 2,6-BIS(IMINO)PYRIDYL COMPLEXES FOR C-H AMINATION OF SULFAMATE ESTERS

被引：6

作者：

Bon, Jennifer L. ^{[1
]}

Blakey, Simon B. ^{[1
]}

机构：

[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

来源：

HETEROCYCLES | 2012年 / 84卷 / 02期

基金：

美国国家科学基金会;

关键词：

C-H Amination; Catalysis; Ruthenium Catalyst; 2,6-Bis(imino)pyridyl Ligand; Sulfamate Ester; CATALYTIC-ACTIVITY; LIGANDS;

D O I：

10.3987/COM-11-S(P)64

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A family of ruthenium(II) 2,6-bis(imino)pyridyl complexes have been developed as a novel catalyst framework for C-H amination. Their synthesis and evaluation is herein described. The reactivity of these catalysts is heavily dependent upon the electronics of the ligand. These complexes are capable of functionalizing the benzylic protons of sulfamate esters with good conversion.

引用

页码：1313 / 1323

页数：11

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