SYNTHESIS OF RUTHENIUM(II) 2,6-BIS(IMINO)PYRIDYL COMPLEXES FOR C-H AMINATION OF SULFAMATE ESTERS

被引：6

作者：

Bon, Jennifer L. ^{[1
]}

Blakey, Simon B. ^{[1
]}

机构：

[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

来源：

HETEROCYCLES | 2012年 / 84卷 / 02期

基金：

美国国家科学基金会;

关键词：

C-H Amination; Catalysis; Ruthenium Catalyst; 2,6-Bis(imino)pyridyl Ligand; Sulfamate Ester; CATALYTIC-ACTIVITY; LIGANDS;

D O I：

10.3987/COM-11-S(P)64

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A family of ruthenium(II) 2,6-bis(imino)pyridyl complexes have been developed as a novel catalyst framework for C-H amination. Their synthesis and evaluation is herein described. The reactivity of these catalysts is heavily dependent upon the electronics of the ligand. These complexes are capable of functionalizing the benzylic protons of sulfamate esters with good conversion.

引用

页码：1313 / 1323

页数：11

共 50 条

[1] Synthesis of Tridentate 2,6-Bis(imino)pyridyl Ruthenium(II) Complexes with N-Heterocyclic Carbene Ligands: Activation of Imidazolium Salts
Yoo, Hyojong
Berry, Donald H.
INORGANIC CHEMISTRY, 2014, 53 (21) : 11447 - 11456
[2] Cyclopropanation of styrene with ethyl diazoacetate catalyzed by chiral and achiral ruthenium 2,6-bis(imino)pyridyl complexes
Bianchini, C
Lee, HM
ORGANOMETALLICS, 2000, 19 (10) : 1833 - 1840
[3] Synthesis of tridentate 2,6-bis(imino)pyridyl aminechlorohydro ruthenium(II) complexes: The convenient use of amine hydrochlorides to generate metal-hydride
Kim, Jin Kyung
Berry, Donald H.
Yoo, Hyojong
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (09) : 1895 - 1898
[4] Effect of alkylaluminum on ethylene polymerization catalyzed by 2,6-bis(imino)pyridyl complexes of Fe(II)
Wang, Q
Li, LD
Fan, ZQ
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (08) : 1599 - 1606
[5] Syntheses and structures of blue luminescent zinc(II) complexes with 2,6-bis(imino)pyridyl ligands
Fan, RQ
Zhu, DS
Mu, Y
Su, Q
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2004, 20 (06) : 801 - 803
[6] Structural and catalytic aspects of copper(II) complexes containing 2,6-bis(imino)pyridyl ligands
Shaban, S. Y.
Ramadan, A. M.
Van Eldik, R.
JOURNAL OF COORDINATION CHEMISTRY, 2012, 65 (14) : 2415 - 2431
[7] Structure of new tridentate 2,6-bis(imino)-pyridyl ruthenium(II) complexes with 2,3,6-trimethyl benzenamine ligand
J. K. Kim
H. Yoo
Journal of Structural Chemistry, 2012, 53 : 347 - 353
[8] Structure of new tridentate 2,6-bis(imino)-pyridyl ruthenium(II) complexes with 2,3,6-trimethyl benzenamine ligand
Kim, J. K.
Yoo, H.
JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 53 (02) : 347 - 353
[9] Syntheses, structures, and luminescent properties of copper(II) complexes based on 2,6-bis(imino)pyridyl ligands
Fan, Rui-Qing
Wang, Ping
Yang, Yu-Lin
Zhang, Yan-Jiao
Yin, Yan-Bing
Hasi, Wuliji
POLYHEDRON, 2010, 29 (14) : 2862 - 2866
[10] Syntheses and Structures of Blue-Luminescent Mercury(II) Complexes with 2,6-Bis(imino)pyridyl Ligands
Fan, Ruiqing
Yang, Yulin
Yin, Yanbin
Hasi, WuLiJi
Mu, Ying
INORGANIC CHEMISTRY, 2009, 48 (13) : 6034 - 6043

← 1 2 3 4 5 →